Bond — the series · Fluid Flow & Aerodynamics

How big before gravity shows. A drop's height over its width against the Bond number, which is the ratio of its weight to the force its own skin can supply. The number is one where those two are equal, and by then the drop is a bun: it is one per cent from a ball at Bo = 0.0079, five per cent at 0.054 and ten at 0.13. Every one of those is below one, and the first is below it by a factor of a hundred and twenty-six.

The size a drop is allowed

The Bond number sets a drop's weight against the force its own skin can supply, and it is one when they are equal. By then the drop is a bun — it is a per cent from being a ball at Bond number 0.0079, which is a water drop half a millimetre across.

part 1 · regimes

A drop fed into a tube, to scale, up to the largest one it can hold. Six members of the family of static drops a tube of radius half a capillary length holds, drawn to scale and hung from the rim, with their volumes in cubic capillary lengths. The drop grows from a shallow cap through a hemisphere to a bulb with a neck. The last is the fold: no static drop on this tube holds more, and it holds 76 per cent of what Tate's law says the tube can carry.

The drop falls at a fold

Tate's law says a drop leaves a tube when its weight equals the tension round the rim. No force balance decides it. A tube holds a family of static drops, the family has a largest member, and the drop falls because there is no static shape with more liquid in it — which Tate's balance overestimates by a quarter on a millimetre tube and underestimates on a wide one.

part 2 · regimes

Four tubes to scale, and the level Jurin's law gives each. Water rising in tubes of radius half a capillary length to four, drawn to one scale, with the level of the liquid far outside the tubes at the bottom. The red line in each tube is Jurin's height, 2ℓ²/R. In the narrow tube the surface is nearly flat and sits on it. In the wide ones the liquid gathers in a rim at the wall, the centre hardly rises, and Jurin's level runs through the middle of a surface that is nowhere near it — while still being its exact average.

A law that is exact as an average

Jurin's law gives the height water climbs in a tube as twice the square of the capillary length over the radius. As a statement about the height it is an approximation for narrow tubes. As a statement about the mean height of everything lifted it is exact for every tube — and a wide tube shows what the average was hiding: a rim of water at the wall and almost nothing in the middle.

part 3 · regimes

What a tilted pane holds is a difference of two cosines. The largest ridge a tilted plate holds, as a cross-section in square capillary lengths, against the tilt, for clean glass (advancing 30°, receding 10°), a plastic (90°, 70°) and a water-repellent coating (115°, 95°): the force balance (cos θᵣ − cos θₐ) ÷ sin α, and, as points, the areas of drops shot from Young–Laplace, which do not use it. Clean glass holds least, not because water sticks to it less but because on a surface it wets well the two cosines are nearly equal.

The force a contact line holds is a range

Capillary rise and the drop on a window are usually drawn with one contact angle, and a contact line with one angle makes a force that is a single number. A real contact line pins, and stops anywhere between a receding and an advancing angle. The force it holds is then a range, as static friction is, and its width is surface tension times the difference of two cosines. A tube holds its column at any height in the range, so which way the meniscus last moved matters more than how patchy the wall is — and a tilted pane holds a drop only as large as that difference allows.

part 4 · regimes

Past its threshold a ridge slides at a speed its angles set. The steady speed of a ridge of liquid one square capillary length in cross-section, as a capillary number, against the plate's tilt, on three surfaces. Below each surface's threshold it is stuck. Past it the speed rises from zero, linearly at first, as far as the tilt allows. On clean glass the curve barely exists: between its threshold and the speed at which its uphill contact line fails there is a sliver of tilt, and a ridge pushed past that cannot slide steadily with a clean trailing edge.

A sliding drop is held harder the faster it goes

A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.

part 5 · regimes