Bulk viscosity — the series
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The viscosity nobody uses
A fluid has two viscosities. One resists a change of shape and appears in every viscous calculation; the other resists a change of volume, was set to zero by Stokes in 1845 in a paper that says he had no argument for doing so, and for carbon dioxide is fifteen hundred times larger than the one everybody quotes.
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The largest bulk viscosity is the first to expire
A bulk viscosity is not a separate property of a gas. It is the time a molecule's internal motion takes to catch up with a compression, multiplied by the pressure and by how much heat capacity lags, and read from below that time's frequency. So the coefficient that is largest is the one that stops being a coefficient soonest: carbon dioxide's fifteen-hundred-fold value is ten per cent wrong at 24 kHz, and on Mars it is two speeds of sound in the audible band.
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A bulk viscosity holds a shock together until it splits
Carbon dioxide's bulk viscosity, fifteen hundred times its shear viscosity, is a vibrational relaxation seen from below its frequency, and a shock is where that description is tested hardest. Carried through a steady shock, the relaxation reproduces the coefficient exactly for the weakest shocks. At a pressure rise of nine and a half per cent the shock outruns the frozen sound speed and splits into a jump and a tail, and the coefficient then draws a shock that does not exist.