Series

Deborah — the series

2 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. Storage and loss moduli, for one relaxation time and for a spectrum. The two moduli of a Maxwell fluid and of a Rouse chain, against frequency in units of the longest relaxation time. One relaxation time makes the storage modulus overtake the loss modulus at λω = 1 and then leave it behind without limit. A spectrum of 1000 modes makes them rise together as the square root of frequency and stay a fixed ratio apart, so the material never becomes the solid the single time predicts.

    A solid, if it is not given time

    The Deborah number is the only such group with no fluid in it at all — two times and nothing else — and it says a material is a solid or a liquid depending on how long anybody watches. What it throws away is that no real material has one time, and the spectrum it replaces changes the answer in kind rather than in degree.

    part 1 · regimes
  2. Shaken at the right frequency, a liquid with one relaxation time moves sixteen hundred times the flow its viscosity allows. The amplitude of the oscillating flow rate over the steady Poiseuille flow the same pressure-gradient amplitude drives through a Newtonian liquid of the same zero-shear viscosity, against the frequency, in a tube 1 cm in radius. A Maxwell liquid with λ = 1 s and η₀ = 30 Pa·s peaks at 1660 times at 6.63 Hz and again at 317 times near 15.2 Hz; a Rouse spectrum with the same longest time and viscosity reaches 20.2 at 19.8 Hz; the Newtonian liquid only falls, to 0.99 at 30 Hz.

    A liquid with one relaxation time rings in a tube, and a spectrum of times silences it

    Push a viscoelastic liquid back and forth along a rigid tube and, if its relaxation time is long against the cycle, the tube becomes a cavity for shear waves in the liquid itself. At the cavity's resonance a wormlike-micelle solution in a tube one centimetre across moves sixteen hundred times the flow a Newtonian liquid of the same viscosity would. The Deborah number says when the liquid is elastic enough to ring; it cannot say whether it will, because a polymer with a spectrum of relaxation times and the same longest one damps the same resonance to a factor of twenty.

    part 2 · regimes

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