Knudsen — the series
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Where a fluid stops being one
The Knudsen number is the mean free path over the size of the thing, and at one a molecule crosses the whole channel between collisions. The continuum equations with a no-slip wall are already one per cent wrong at one part in five hundred and ninety-four, which is a factor nothing about the definition would suggest.
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Slip is a memory of one mean free path
A molecule arriving at a wall last collided about a mean free path away and carries the velocity from there. Averaged over arrivals and departures, that leaves the gas at the wall moving — by two per cent of the centreline speed at a Knudsen number of a hundredth, and sixty per cent more flow through a microchannel at a tenth.
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A thinning gas flows least at one free path across, and then more without end
Pump the gas out of a narrow channel and, for the same pressure gradient, less of it flows — until the channel is about one mean free path high. Thinner than that, more flows, and between infinite plates the flow rate climbs without limit, because the molecules carrying it are the ones skimming along the walls, whose flights only collisions with other molecules can end. Knudsen measured the minimum in 1909. The linearised kinetic equation puts it at a reduced flow rate of 1.538, at a Knudsen number of 0.83, and shows it is not a dip below the two closed forms but a place far above both.