Series

Non-newtonian — the series

4 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. Seven fluids in one pipe at one pressure gradient. Velocity profiles of power-law fluids in a round pipe, all at the same pressure gradient and the same consistency, scaled to the fastest. A shear-thinning fluid (n below one) is flatter in the middle and steeper at the wall; a shear-thickening one is the reverse. The flattening is often called plug-like, which invites the reading that the fluid is moving more freely — what has actually happened is that all the shear has been pushed into a thin annulus at the wall, which is the expensive place to put it.

    A viscosity that depends on the question

    Blood, paint, molten polymer and drilling mud have no viscosity. They have a relation between stress and strain rate that is not proportional, so the ratio of the two depends on how hard they are being sheared — and an instrument that reports one number is reporting a property of itself.

    part 1 · viscous
  2. The core that does not move, and where its edge is. Four velocity profiles at the same pressure gradient and four yield stresses. The shear stress in a pipe is G r/2 whatever the fluid is — that is a force balance and not a constitutive law — so the fluid is unyielded exactly inside r = 2 tau_y/G, and the plug radius is known before anything is solved.

    The core that does not move

    Toothpaste in a tube has a region in the middle that is not being sheared at all, and its edge is at a radius you can write down before solving anything. Four things about that core are exact, and one of them is that the fluid does not flow below a threshold — not slowly, at all.

    part 2 · viscous
  3. Four fluids under the same stress, and the four profiles that result. Each fluid carries the same linear stress and answers it differently: a Newtonian fluid with a parabola, a shear-thinning one with a blunter profile, a shear-thickening one with a sharper one, and a Bingham plastic with a plug in the middle where the stress is below its yield point.

    The stress a pipe knows

    A capillary viscometer measures a pressure drop and a flow rate and reports a viscosity. The first half of that inference is a force balance and is exact for any fluid there is; the second needs the slope of a whole flow curve, which is the experiment the instrument was bought to avoid.

    part 3 · viscous
  4. The flow stops and the stress does not. Shear stress against time for a fluid sheared at a constant rate for two seconds and then left alone. Nothing is moving after the second mark and the fluid is still stressed: 37 per cent of the peak one relaxation time later, and 0.7 per cent after five.

    The fluid that has not finished its last deformation

    Shear a polymer solution for two seconds and stop. Nothing is moving and the fluid is still stressed — 37 per cent of the peak one relaxation time later, and still measurably stressed after five. Two histories imposing exactly the same total strain leave it in states differing by a factor of 3.7.

    part 4 · viscous

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