Series

Real gas — the series

2 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. γ for air, against temperature. The ratio of specific heats for air as a mixture of nitrogen and oxygen, with the vibrational mode filling according to the Einstein function. It is 1.400 at room temperature, where only translation and rotation are available; 1.337 at a thousand kelvin; and 1.288 at six thousand. Every compressible result on this site has used 1.4, and that is the value for a gas that is not hot — which, behind any shock worth drawing, it is not.

    When gamma stops being a number

    Every compressible result on this site has used γ = 1.4, which counts the ways a nitrogen molecule can hold energy at room temperature. Behind a Mach 10 shock the gas is at 3,800 kelvin and the count is different — and the pressure barely moves while the temperature falls by fifteen per cent.

    part 1 · compressible
  2. The temperature behind a shock, which is not the jump condition's. The static temperature along the flow behind a Mach 6 normal shock, with the frozen value the jump conditions give and the equilibrium value they give a long way behind. The gas arrives at 2382 K and settles at 2059, over about four tenths of a millimetre.

    A gas that has not finished being shocked

    The jump conditions give the state a long way behind a shock. Immediately behind it the molecules have not started vibrating yet, so the temperature is 2,382 K where the equilibrium answer is 2,059 — and the gas takes four tenths of a millimetre to get from one to the other.

    part 2 · compressible

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