Series
Real gas — the series
2 essays on one idea, from the one that introduces it to the one that assumes the rest.
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When gamma stops being a number
Every compressible result on this site has used γ = 1.4, which counts the ways a nitrogen molecule can hold energy at room temperature. Behind a Mach 10 shock the gas is at 3,800 kelvin and the count is different — and the pressure barely moves while the temperature falls by fifteen per cent.
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A gas that has not finished being shocked
The jump conditions give the state a long way behind a shock. Immediately behind it the molecules have not started vibrating yet, so the temperature is 2,382 K where the equilibrium answer is 2,059 — and the gas takes four tenths of a millimetre to get from one to the other.