Concept

Constitutive law — where it appears

The relation between a material's stress and its deformation, which is a property of the material rather than a consequence of the equations of motion. Newton's is the simplest, and every departure from it defines a different kind of fluid.

Named by 8 essays across 4 fields — each of them below, with the objects they name alongside it.

The Hugoniot of a gas that can burn, and the gap in the middle of it. Pressure against specific volume, both scaled on the unburnt gas. The lower curve is the ordinary shock Hugoniot, which passes through the initial state because a jump of zero strength satisfies mass, momentum and energy. Adding a heat release lifts it away, and the initial state now sits in a region no wave can reach: between the two branches a Rayleigh line would need a positive slope, and its slope is minus the square of the mass flux. A burning gas has no weak waves available to it at all.

The other branch of the same curve

Put heat into the jump conditions and the Hugoniot lifts away from the initial state, leaving a gap no wave can occupy. A burning gas has no weak waves: it must run supersonically or subsonically, and the conservation laws pick the first speed exactly and say nothing at all about the second.

compressible · Detonation
The chord and the tangent, which are the two speeds. The flux of a conserved quantity against its own density, for a wide river and for traffic. At any point the slope of the chord from the origin is the speed the material moves at, and the slope of the tangent is the speed a disturbance moves at. They are the same number only if the curve is a straight line through the origin. For the river the tangent is five-thirds of the chord at every depth; for traffic the tangent turns negative above half the jam density while the chord never does.

A wave nothing in it travels with

A flood crest moves at five-thirds the speed of the water it is made of, at every depth, whatever the roughness and whatever the slope. A traffic wave moves backwards through cars that are all going forwards. Neither result contains a momentum equation.

kinematics · Kinematic waves
Seven fluids in one pipe at one pressure gradient. Velocity profiles of power-law fluids in a round pipe, all at the same pressure gradient and the same consistency, scaled to the fastest. A shear-thinning fluid (n below one) is flatter in the middle and steeper at the wall; a shear-thickening one is the reverse. The flattening is often called plug-like, which invites the reading that the fluid is moving more freely — what has actually happened is that all the shear has been pushed into a thin annulus at the wall, which is the expensive place to put it.

A viscosity that depends on the question

Blood, paint, molten polymer and drilling mud have no viscosity. They have a relation between stress and strain rate that is not proportional, so the ratio of the two depends on how hard they are being sheared — and an instrument that reports one number is reporting a property of itself.

viscous · Non-newtonian
Where Einstein's line stops being the measurement. The viscosity of a suspension of rigid spheres relative to the liquid's, against the volume fraction. Einstein's 1 + 5φ/2 is exact for one sphere and holds while the spheres cannot feel one another, which is up to about five per cent by volume. Batchelor and Green's two-sphere term takes it a little further; beyond about a fifth nothing derived works and the curve drawn is a fit, which diverges at a maximum packing that is itself a measurement.

A viscosity made of particles

Stir rigid spheres into a liquid and the mixture is thicker, by five halves of the volume fraction. Einstein's coefficient is not an empirical constant — it is a dissipation calculation on one sphere — and doing it as an energy rather than as a stress shows that four-fifths of it comes from somewhere nobody mentions.

viscous · Suspension
Storage and loss moduli, for one relaxation time and for a spectrum. The two moduli of a Maxwell fluid and of a Rouse chain, against frequency in units of the longest relaxation time. One relaxation time makes the storage modulus overtake the loss modulus at λω = 1 and then leave it behind without limit. A spectrum of 1000 modes makes them rise together as the square root of frequency and stay a fixed ratio apart, so the material never becomes the solid the single time predicts.

A solid, if it is not given time

The Deborah number is the only group on this site with no fluid in it — two times and nothing else — and it says a material is a solid or a liquid depending on how long anybody watches. What it throws away is that no real material has one time, and the spectrum it replaces changes the answer in kind rather than in degree.

regimes · Deborah
The core that does not move, and where its edge is. Four velocity profiles at the same pressure gradient and four yield stresses. The shear stress in a pipe is G r/2 whatever the fluid is — that is a force balance and not a constitutive law — so the fluid is unyielded exactly inside r = 2 tau_y/G, and the plug radius is known before anything is solved.

The core that does not move

Toothpaste in a tube has a region in the middle that is not being sheared at all, and its edge is at a radius you can write down before solving anything. Four things about that core are exact, and one of them is that the fluid does not flow below a threshold — not slowly, at all.

viscous · Non-newtonian
Four fluids under the same stress, and the four profiles that result. Each fluid carries the same linear stress and answers it differently: a Newtonian fluid with a parabola, a shear-thinning one with a blunter profile, a shear-thickening one with a sharper one, and a Bingham plastic with a plug in the middle where the stress is below its yield point.

The stress a pipe knows

A capillary viscometer measures a pressure drop and a flow rate and reports a viscosity. The first half of that inference is a force balance and is exact for any fluid there is; the second needs the slope of a whole flow curve, which is the experiment the instrument was bought to avoid.

viscous · Non-newtonian
The column in height and time: a falling interface, a rising shock, a fan. A batch settling test from a uniform φ₀ = 0.1, height above the bottom against time, both scaled on the column height and the single-particle settling time. The interface with clear water (thick) falls in a straight line at 0.4538; the sediment shock rises from the bottom at 0.1484 until the two meet at t = 1.661, height 0.2464; the thin lines are characteristics of the fan, each carrying one concentration between 0.317 and packing, and the interface bends as it crosses them. Dots are the finite-volume solve on 400 cells: the interface and the sediment front.

The column the chord rule cannot settle

A suspension settling in a closed column is a kinematic wave, and its flux curve bends both ways. At the top the chord rule works: clear water meets the suspension at a single falling front. At the bottom it does not, and the bed grows behind a shock that stops short of packing and a graded layer beneath it — so the interface, instead of arriving, slows for ever.

kinematics · Kinematic waves

Named alongside it

The objects these essays reach for when they reach for this one.

MeasurementConservationDiscontinuityModel limitNon-newtonianPipe flowSignal speedViscosityCharacteristicsDissipationKinematic-waveMass conservation

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