Non-newtonian — where it appears
Named by 6 essays across 3 fields — each of them below, with the objects they name alongside it.
A viscosity that depends on the question
Blood, paint, molten polymer and drilling mud have no viscosity. They have a relation between stress and strain rate that is not proportional, so the ratio of the two depends on how hard they are being sheared — and an instrument that reports one number is reporting a property of itself.
The core that does not move
Toothpaste in a tube has a region in the middle that is not being sheared at all, and its edge is at a radius you can write down before solving anything. Four things about that core are exact, and one of them is that the fluid does not flow below a threshold — not slowly, at all.
The stress a pipe knows
A capillary viscometer measures a pressure drop and a flow rate and reports a viscosity. The first half of that inference is a force balance and is exact for any fluid there is; the second needs the slope of a whole flow curve, which is the experiment the instrument was bought to avoid.
The fluid that has not finished its last deformation
Shear a polymer solution for two seconds and stop. Nothing is moving and the fluid is still stressed — 37 per cent of the peak one relaxation time later, and still measurably stressed after five. Two histories imposing exactly the same total strain leave it in states differing by a factor of 3.7.
The wall a melt really does slip on
For a simple liquid the slip length is under two nanometres, which is why no-slip is safe everywhere. For an entangled polymer melt it is a millimetre, which is larger than the die it is being pushed through — so the melt moves as a plug and the viscosity a rheometer reports is a property of the instrument.
A liquid with one relaxation time rings in a tube, and a spectrum of times silences it
Push a viscoelastic liquid back and forth along a rigid tube and, if its relaxation time is long against the cycle, the tube becomes a cavity for shear waves in the liquid itself. At the cavity's resonance a wormlike-micelle solution in a tube one centimetre across moves sixteen hundred times the flow a Newtonian liquid of the same viscosity would. The Deborah number says when the liquid is elastic enough to ring; it cannot say whether it will, because a polymer with a spectrum of relaxation times and the same longest one damps the same resonance to a factor of twenty.
Named alongside it
The objects these essays reach for when they reach for this one.
MeasurementConstitutive lawModel validityPipe flowViscoelasticityDeborah numberPolymerPower lawRegimeRelaxation timeShear rateShear stress