Concept

Viscoelasticity — where it appears

The property of a material that stores some of the work done in deforming it and dissipates the rest, so that its response depends on how fast it is asked. Which behaviour dominates is set by the ratio of its own relaxation time to the time of the flow.

Named by 3 essays across 3 fields — each of them below, with the objects they name alongside it.

The flow stops and the stress does not. Shear stress against time for a fluid sheared at a constant rate for two seconds and then left alone. Nothing is moving after the second mark and the fluid is still stressed: 37 per cent of the peak one relaxation time later, and 0.7 per cent after five.

The fluid that has not finished its last deformation

Shear a polymer solution for two seconds and stop. Nothing is moving and the fluid is still stressed — 37 per cent of the peak one relaxation time later, and still measurably stressed after five. Two histories imposing exactly the same total strain leave it in states differing by a factor of 3.7.

viscous · Non-newtonian

Three dies, one melt, three flow curves. The apparent flow curve a capillary rheometer reports, for three dies whose radii differ by a factor of four. A material property cannot depend on the instrument, so the fact that these three do not lie on one another is a measurement of something other than a viscosity. The single curve drawn beneath them is what the same melt gives with the wall condition set to no slip.

The wall a melt really does slip on

For a simple liquid the slip length is under two nanometres, which is why no-slip is safe everywhere. For an entangled polymer melt it is a millimetre, which is larger than the die it is being pushed through — so the melt moves as a plug and the viscosity a rheometer reports is a property of the instrument.

misconceptions · The no-slip condition

Shaken at the right frequency, a liquid with one relaxation time moves sixteen hundred times the flow its viscosity allows. The amplitude of the oscillating flow rate over the steady Poiseuille flow the same pressure-gradient amplitude drives through a Newtonian liquid of the same zero-shear viscosity, against the frequency, in a tube 1 cm in radius. A Maxwell liquid with λ = 1 s and η₀ = 30 Pa·s peaks at 1660 times at 6.63 Hz and again at 317 times near 15.2 Hz; a Rouse spectrum with the same longest time and viscosity reaches 20.2 at 19.8 Hz; the Newtonian liquid only falls, to 0.99 at 30 Hz.

A liquid with one relaxation time rings in a tube, and a spectrum of times silences it

Push a viscoelastic liquid back and forth along a rigid tube and, if its relaxation time is long against the cycle, the tube becomes a cavity for shear waves in the liquid itself. At the cavity's resonance a wormlike-micelle solution in a tube one centimetre across moves sixteen hundred times the flow a Newtonian liquid of the same viscosity would. The Deborah number says when the liquid is elastic enough to ring; it cannot say whether it will, because a polymer with a spectrum of relaxation times and the same longest one damps the same resonance to a factor of twenty.

regimes · Deborah

Named alongside it

The objects these essays reach for when they reach for this one.

Non-newtonian Deborah number Measurement Model validity Polymer Relaxation time Boundary condition Constitutive law Convolution Instrument Memory kernel Model limit

All concepts