Mean free path — where it appears
Named by 6 essays across 3 fields — each of them below, with the objects they name alongside it.
What a flow is
A fluid is made of molecules and nobody models it that way. Treating it as a continuous field with a velocity at every point is an approximation, an extremely good one, and knowing why it works is knowing where it stops.
Where a fluid stops being one
The Knudsen number is the mean free path over the size of the thing, and at one a molecule crosses the whole channel between collisions. The continuum equations with a no-slip wall are already one per cent wrong at one part in five hundred and ninety-four, which is a factor nothing about the definition would suggest.
The discontinuity that has a thickness
The jump conditions do not contain the viscosity, which is why they are exact. The thickness is entirely viscosity — 289 nanometres at Mach 1.5, 35 at Mach 5, against a mean free path of 64. At Mach five the continuum equations have produced a structure thinner than the distance between collisions.
Slip is a memory of one mean free path
A molecule arriving at a wall last collided about a mean free path away and carries the velocity from there. Averaged over arrivals and departures, that leaves the gas at the wall moving — by two per cent of the centreline speed at a Knudsen number of a hundredth, and sixty per cent more flow through a microchannel at a tenth.
A gas's viscosity ignores its pressure until the free path reaches the walls
Maxwell predicted in 1860 that a gas's viscosity does not depend on its density — halve the pressure and half as many molecules carry momentum across the flow, each twice as far — and measured it with swinging discs in 1866: unchanged from an atmosphere to a sixtieth of one. Solved across every pressure with the kinetic equation, the shear a gas transmits between two plates obeys him over five decades and then, once the free path reaches the gap, falls in proportion to the pressure. A millimetre gap reads half the true viscosity at fifteen pascals, and a vacuum gauge reads pressure from exactly that fall.
A thinning gas flows least at one free path across, and then more without end
Pump the gas out of a narrow channel and, for the same pressure gradient, less of it flows — until the channel is about one mean free path high. Thinner than that, more flows, and between infinite plates the flow rate climbs without limit, because the molecules carrying it are the ones skimming along the walls, whose flights only collisions with other molecules can end. Knudsen measured the minimum in 1909. The linearised kinetic equation puts it at a reduced flow rate of 1.538, at a Knudsen number of 0.83, and shows it is not a dip below the two closed forms but a place far above both.
Named alongside it
The objects these essays reach for when they reach for this one.
ContinuumKnudsen numberSlipBoundary conditionKinetic theoryModel validityViscosityMeasurementTransportAsymptoticsDimensionlessDiscontinuity