Concept

Bubble — where it appears

A pocket of gas or vapour inside a liquid, bounded by an interface whose tension pushes inward with a pressure of 2σ/r. It grows once the surrounding liquid falls below the pressure that balances that tension, and a bubble filling a tube's bore rises at a speed set by the bore rather than by its own length.

Named by 11 essays across 5 fields — each of them below, with the objects they name alongside it.

$Two-thirds to one, and nothing outside it. The drag on a spherical drop as a fraction of Stokes' drag on a rigid sphere of the same size, against the ratio of the viscosities. It runs from exactly two-thirds for a clean gas bubble to exactly one for a rigid particle and takes no value outside that range, however light or heavy the drop is — the formula has no density in it anywhere. A drop of water in air and a drop of mercury in water sit at opposite ends of it.$

The surface that moves with the flow

A clean gas bubble feels two-thirds of the drag a rigid sphere of the same size would, and the formula has no density in it anywhere. What buys the third is that the bubble's surface is free to move — and real bubbles in ordinary water do not get it, for a reason that is a millionth of a per cent of the water by mass.

viscous · Mobile interface

A litre of water at the crown carries 77 mL of gas it cannot hold. The volume of free gas a litre of air-saturated water can release at a siphon's crown, at the crown's own pressure, against that pressure, on a logarithmic scale, at three temperatures. It is zero at atmospheric and grows without limit towards the vapour pressure. At the reference siphon's starting crown pressure of 51.5 kPa it is 20.6 mL, a supersaturation of 2.02; at the frictionless floor of 23.0 kPa it is 76.7 mL, a supersaturation of 4.79. Cold water carries more: 87.4 mL at 5 °C. This is the equilibrium bound — what would come out if the water stayed long enough, which it does not.

The air that breaks a siphon nothing else can

A running siphon's heights cannot break it, and its friction only postpones the moment it is most exposed. What does break a siphon that has run for a day is the air dissolved in its water, which the crown's low pressure leaves the water carrying far more of than it can hold — and which gathers only once the flow is too slow to carry a bubble away.

misconceptions · Siphon

In clean water a bubble rises nearly three times as fast as the same bubble in tap water. The terminal rise speed of an air bubble in water at 20 °C against its radius, from buoyancy balanced against drag: with a clean, shear-free surface using Moore's law, and with a surface immobilised by contamination using the rigid-sphere correlation. At 0.3 mm the clean bubble rises at 13.0 cm/s against 6.7; at 0.5 mm at 31.0 against 11.2, a factor of 2.76. Beyond a radius of 0.47 mm the clean bubble's Weber number passes one, its shape flattens, and a spherical calculation stops describing it; that region is shaded. Nothing about the bubble's size, gas or liquid changes between the two curves — only whether its surface can move.

The vorticity a clean surface cannot refuse

A clean bubble's surface cannot hold a shear stress, and it is easy to conclude that it makes no vorticity. On a curved surface it must carry exactly 2κu — three times the speed over the radius at a sphere's equator, whatever the Reynolds number. That is so much weaker than a rigid wall's that the flow stays irrotational to leading order, and the bubble's drag is the dissipation of that irrotational flow: 48/Re, three to ten times below a rigid sphere's.

kinematics · Boundary conditions

Released, the side-by-side pair collides and the tandem pair parts. The distance between the centres of two cylinders released from rest in an ideal stream and free to move along the line joining them, against time in radii over the stream speed. Side by side they are drawn together and collide — neutrally buoyant ones released four radii apart after 6.5, bubbles, with no mass of their own, after 4.82. In tandem they are pushed apart and keep going.

A pair set free in a stream collides or parts

Two cylinders held in an ideal stream pull together side by side and push apart in tandem. Let them go and the forces become a motion, and the motion has a law of its own: the stream's force on each is exactly the slope of how large the pair looks from far away, so the pair moves to look bigger. Side by side that means closing, and the fluid squeezed out of the gap costs so little that nothing stops them: released four radii apart they collide in six and a half radii of stream. In tandem it means parting, for good.

inviscid · Dalembert

A free pair turns, and forty-five degrees decides

Two cylinders in an ideal stream move to look bigger to it: side by side they close, in tandem they part. Free to turn as well, a staggered pair swings towards side by side — and does not stop there, because nothing in an ideal fluid damps the swing. Whether it then collides or flies apart is decided, far apart, by one angle and a theorem: the stream's pull on the pair falls as the inverse square of the spacing, and for such a force the sign of the energy alone decides, which changes at exactly forty-five degrees.

inviscid · Dalembert

Dissolved gas takes height from the largest nuclei first. The tallest crown a siphon runs over, against the radius of its largest nucleus at the reservoir, when a nucleus at the crown must neither break the water at once nor grow to break it by diffusion, for water at 0, 10, 30, 60 and 100 per cent of saturation. Fully degassed water gives the static limit. For a one-micron nucleus, gas below about a fifth of saturation changes nothing — 14.41 m against 14.41 — and saturated water brings it to 10.7 m. A five-micron nucleus in saturated water breaks the siphon at 2.4 m.

A crown dissolves its nuclei or breaks on them, and fast

A siphon of degassed water runs until its crown's tension reaches the breaking threshold of its largest nucleus. A nucleus lodged at the crown does not stay the size it arrived: it gains or loses gas by diffusion, and across a micron diffusion takes milliseconds, so the crown gives its verdict almost at once. Every stable nucleus loses gas unless the water holds more than half the crown's tension, and past a knee in gas content, dissolved air takes height from a siphon's crown that no amount of further degassing gives back.

misconceptions · Siphon

A thousandth of a monolayer holds a bubble still

A clean bubble rising slowly through water feels two-thirds of a rigid sphere's drag, and real bubbles almost never do, because surfactant swept to the rear holds the surface still over a cap there. Solving the flow with the cap in it shows how little that takes. The drag runs ahead of the area covered — half-way to rigid with a third of the surface held — and the surfactant needed is set by the viscous stress, not by the surface tension. For a bubble a tenth of a millimetre across, a thousandth of a monolayer, spread as a cap, makes it rise within a few per cent of a solid ball.

viscous · Mobile interface $Below the bubbles' resonance the mixture is slow; above its stop band it is faster than water. The phase speed of sound in water carrying millimetre air bubbles, against frequency, at void fractions of 10⁻⁴, 10⁻³ and 10⁻². At low frequency each is Wood's mixture speed with the gas isothermal — 312 m/s at 10⁻³, not the 366 an adiabatic gas would give. Approaching the bubbles' resonance near 3.2 kHz the speed falls further, then jumps through a stop band in which the wave hardly propagates, and above it the phase speed exceeds water's — at 10⁻³ 1640 m/s at 30 kHz — before returning to 1481 m/s from above.$

Above their resonance, bubbles make water faster

Wood's formula says a pinch of air makes water's sound slower than air's, and it is right at low frequency. Each bubble, though, is a spring with water for its mass, and the wave drives it. Below the bubbles' resonance the mixture is slow; through a band above it no sound propagates at all; and above that band the same bubbly water carries sound faster than pure water does. Even the slow end is not quite Wood's, because a slowly squeezed bubble keeps its heat.

compressible · Speed of sound

Below 9.8 µm in silicone oil, a gradient of a degree per millimetre outruns gravity. The speed of a clean air bubble in 10 cSt silicone oil against its radius, on logarithmic axes: migrating in a gradient of 1 K/mm, which grows in proportion to the radius, and rising under its weight, which grows with its square. They cross at 9.81 µm and 31 µm/s. The crossing radius, 3|dσ/dT|G/(2ρg), has no viscosity in it: both speeds are set against the same viscous drag.

The warm side pulls a bubble with no force on it

A bubble in a liquid whose temperature varies from place to place moves towards the warm side, with no gravity and nothing pushing it. The surface tension is lower where the liquid is warmer, the surface is pulled towards the cold pole, and the bubble goes the other way. Young, Goldstein and Block's speed comes out of four interface conditions and one more: that the total force on the bubble is zero. That one condition removes the point force a sinking or rising body always carries, so the bubble's disturbance dies a hundred times faster with distance, and the radius at which it balances its own buoyancy has no viscosity in it.

viscous · Mobile interface $A spread of sizes smears the stop band and pushes the fast band up. The phase speed of sound against frequency in water carrying air bubbles at a void fraction of 10⁻³: all of one millimetre radius, and spread from 10 µm to 1 mm as n ∝ R^(−q) with q = 0, 3/2 and 10/3. Every cloud starts at Wood's speed, 312 m/s, because at low frequency every bubble is driven below its resonance. The single size jumps through its stop band near 3 to 13 kHz into a fast band. The distributions climb through a band as wide as their resonances, 3.2 kHz for the largest to 301 kHz for the smallest, and the more small bubbles they carry the later they emerge faster than water.$

The more small bubbles a cloud holds, the later it turns fast

Bubbles of one size give water three sound speeds: slow below their resonance, nothing in a stop band, faster than water above it. A cloud of many sizes has every resonance at once, so at any frequency its small bubbles soften it and its large ones stiffen it. The stop band becomes a wide band of attenuation, the fast band survives above it, and where the fast band starts is set by how much of the gas is in the smallest bubbles.

compressible · Speed of sound $The same cap costs a rising bubble a quarter of its speed and a migrating one four-fifths. Speed as a fraction of the clean bubble's against the half-angle of a stagnant cap over the rear: for a bubble migrating in a temperature gradient, and for the same bubble rising under its weight. A 90° cap leaves the rising bubble 74 per cent of its speed and the migrating one 21 per cent; a 120° cap, 68 and 4. The rising bubble can only fall to a rigid sphere's two-thirds; the migrating one falls to nothing.$

A cap that slows a rising bubble stops a migrating one

Surfactant swept to the back of a bubble holds the surface still there, and for a bubble rising under its weight the worst this can do is turn it into a solid sphere and cost it a third of its speed. A bubble migrating in a temperature gradient has no such floor. Its own surface is the engine, and a cap removes the engine as well as raising the drag. A cap over the cold hemisphere leaves a rising bubble three-quarters of its speed and a migrating one a fifth; a cap of 120° leaves the migrating bubble four per cent. The surfactant it takes is set by the tension difference that drives the migration, and that is tiny.

viscous · Mobile interface

Named alongside it

The objects these essays reach for when they reach for this one.

Model limit Boundary condition Potential flow Cavitation d'Alembert's paradox Drag coefficient Hadamard rybczynski Marangoni Stokes flow Surface tension Surfactant Added mass

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