Concept

Surface tension — where it appears

The energy per unit area of a liquid interface, which acts as a force per unit length along it. It scales with a length where every other force in the subject scales with an area or a volume, so its importance is decided by size alone.

Named by 31 essays across 7 fields — each of them below, with the objects they name alongside it.

The Ohnesorge diagram, with the boundaries where they belong. The classical map of jet break-up: the Ohnesorge number against the jet Reynolds number, with the five nozzles placed on it. The three sloping lines are Reitz's transitions in the gas Weber number, and their geometry is computed rather than sketched — a fixed We_g means Oh·Re is fixed, which is a straight line of slope exactly −1 in these coordinates, and a decade in Reynolds number is checked to move each line by exactly one decade. Where they sit is borrowed; that they are straight and parallel is not. A nozzle below and to the right of the last line atomises.

Where a jet stops being a jet

A tap makes drops a few centimetres down, a garden hose makes a stream that carries, a sprayer makes a mist and a diesel injector makes fog. Same liquid, same mechanism, four regimes — and the number that separates them is not the jet's inertia but the surrounding air's.

regimes · Atomisation
How big before gravity shows. A drop's height over its width against the Bond number, which is the ratio of its weight to the force its own skin can supply. The number is one where those two are equal, and by then the drop is a bun: it is one per cent from a ball at Bo = 0.0079, five per cent at 0.054 and ten at 0.13. Every one of those is below one, and the first is below it by a factor of a hundred and twenty-six.

The size a drop is allowed

The Bond number sets a drop's weight against the force its own skin can supply, and it is one when they are equal. By then the drop is a bun — it is a per cent from being a ball at Bond number 0.0079, which is a water drop half a millimetre across.

regimes · Bond
A falling drop is a bun, not a tear. The shape of a drop pressed on by the air it is falling through, computed by matching the Legendre component of a sphere's own potential-flow pressure distribution against the change in curvature it produces. The result is oblate — flattened along the direction of travel — because the pressure is high at the poles and low round the equator. The teardrop of every illustration has the wrong symmetry entirely: a drop in free fall has no up, and one at terminal speed is being pressed on from in front.

The drop that is not a tear

A falling raindrop is flattened along the direction it is going, by the pressure of the air passing it rather than by its own weight, and the group that decides is the Weber number. The teardrop of every illustration has the wrong symmetry entirely — there is no up in the problem it is drawn for.

regimes · Drop shape
Twice as fast is not twice as thick. The film a plate carries out of water, against the speed it is withdrawn at, both logarithmic. The slope is exactly two-thirds, so doubling the speed thickens the film by 58.7 per cent and never by more. The open marks are outside the range the derivation holds in — above a capillary number of about a hundredth the film is no longer thin against the capillary length, and the measured thickness leaves this line.

What a plate takes with it

Pull a plate out of a bath and it comes out wet. How wet is not set by the plate, the bath or how much liquid there is, but by a competition in a region a fraction of a millimetre long that nobody looking at the plate can see — and the film goes as the two-thirds power of the speed, never as the first.

viscous · Coating
Drop deformation in simple shear, against the capillary number. The shape model's steady deformation for six viscosity ratios. Every curve is linear in the capillary number at small Ca — which is Taylor's result — and every one of them saturates, at 5/2(2λ+3), because the shear's own rotation turns the drop out of the stretching direction. A drop in simple shear cannot be deformed beyond that however hard it is sheared.

The number that cannot break a drop

The capillary number sets the stress that stretches a drop against the stress that holds it round, and it predicts the deformation beautifully. It cannot predict the breakup, because above a viscosity ratio of about four a drop in simple shear cannot be broken at any shear rate — and the theory that says the ratio hardly matters is the same theory that gets the deformation right.

regimes · Capillary
A threshold that is a curve, not a pressure. The tension a rectangular pulse has to reach to make a five-micron bubble run away, against how long the pulse lasts. At a tenth of a microsecond it takes forty bar; at a hundred microseconds it takes 1.05, which is within about one per cent of the static threshold. There is no such thing as the cavitation pressure of this bubble on its own.

A threshold that is also a duration

The cavitation number treats inception as a pressure: below it the liquid tears, above it does not. A five-micron bubble asked to grow in 0.3 microseconds needs 43 bar of tension and the same bubble given a hundred needs 1.05, because it has to make a journey and not merely respond.

applied · Cavitation
100 metres of water, −1.98 MPa absolute at the top. The absolute pressure up a transpiring column 100 metres tall, with the sap rising at 0.25 mm/s through conduits 40 µm across. It starts at 1.3 kPa at the root, falls by 9.79 kPa a metre for gravity and 10.02 for friction, and reaches −1.98 MPa at the top — below zero, which is not a low push but a pull. The pale line is the same column with nothing flowing. The floor is not the vapour pressure but the pore a gas bubble could be drawn through: −2.81 MPa for a 50 nm pore, which this column would reach at 142 metres. A suction pump lifting the same water from a free surface stops at 10.1 metres, because it offers the water somewhere to boil.

Where a liquid does pull

A fluid cannot pull, and the essays that settle what suction is are right about every gas and every liquid with a free surface near it. A liquid with nothing in it to boil on is another matter. Every tree taller than ten metres depends on the difference, and the floor under it is set by the size of a pore rather than by the vapour pressure.

misconceptions · Suction
A tube 10 cm across, spun: the lowest pressure is on the axis. The absolute pressure along a water-filled tube spun about its middle, open to the air at both ends, 5 cm from the axis. In the spinning frame the water is at rest under a centrifugal pull, so the pressure falls from atmospheric at each meniscus to its lowest on the axis, as a parabola. 10 thousand rpm puts −1.3 MPa there, 20 thousand rpm puts −5.4 MPa there, 30 thousand rpm puts −12.2 MPa there and 45 thousand rpm puts −27.6 MPa there. The place the water is stretched hardest is the place furthest from both free surfaces, which is the whole merit of the method: a gas cannot reach the liquid where it is weakest.

A breaking strength that is the size of a flaw

Water can be stretched, and how far is a measurement people have made for a century and a half with instruments that agree with one another and not with the theory. Spinning a tube puts the stretch where no gas can reach it, sealing one caps the stretch at water's density maximum, and every measured number turns out to name the size of the worst cavity in the sample.

misconceptions · Suction
A litre of water at the crown carries 77 mL of gas it cannot hold. The volume of free gas a litre of air-saturated water can release at a siphon's crown, at the crown's own pressure, against that pressure, on a logarithmic scale, at three temperatures. It is zero at atmospheric and grows without limit towards the vapour pressure. At the reference siphon's starting crown pressure of 51.5 kPa it is 20.6 mL, a supersaturation of 2.02; at the frictionless floor of 23.0 kPa it is 76.7 mL, a supersaturation of 4.79. Cold water carries more: 87.4 mL at 5 °C. This is the equilibrium bound — what would come out if the water stayed long enough, which it does not.

The air that breaks a siphon nothing else can

A running siphon's heights cannot break it, and its friction only postpones the moment it is most exposed. What does break a siphon that has run for a day is the air dissolved in its water, which the crown's low pressure leaves the water carrying far more of than it can hold — and which gathers only once the flow is too slow to carry a bubble away.

misconceptions · Siphon
Slip follows the stripes more closely than the shear does. Plan views of a striped surface, with the stripes running across each panel, for a shear at 0°, 30°, 54.7° and 90° to them. The faint arrow is the direction of the shear; the dark one is the slip velocity it produces, whose component along the stripes is the along-stripe slip length times the shear and whose component across them is half that. The slip is turned towards the stripes by 0.0°, 13.9°, 19.5° and 0.0°. It is largest, 19.47°, for a shear at 54.74°, where tan θ = √2. A surface with a tensor for a boundary condition can push a flow sideways, which a scalar slip length never can.

Twice as slippery along as across

A surface of alternating gas and solid stripes lets a liquid slip, and a flow far above it sees one number in place of the pattern — but the number depends on which way the flow goes. Along the stripes it is Philip's logarithm; across them it is exactly half, for a reason that takes one substitution to show. And the logarithm means that the slip is bought by the pattern's period rather than by how much of it is gas.

kinematics · Boundary conditions
A water sheet two millimetres thick leaves the lip above 0.270 m/s. The effective tension of a sheet of water, 2σ − ρU²h per metre of its width, against the speed it is poured at, for sheets one, two and four millimetres thick. At rest every sheet carries the tension of its two surfaces, 145.4 mN/m, and the momentum it carries along itself subtracts from that. A 1 mm sheet reaches zero at 0.382 m/s, a 2 mm sheet reaches zero at 0.270 m/s and a 4 mm sheet reaches zero at 0.191 m/s. Below its own crossing a sheet bent round a lip is pulled onto it; above, it is flung off. The quantity that decides is a tension, not a pressure, and the speed at which it vanishes is the speed of waves along the sheet.

The teapot effect is a tension, not a pressure

A slow pour runs back under a spout and down its outside, and the name it is usually given is the Coandă effect. The Coandă effect borrows the ambient pressure, and a liquid in air has none to borrow. A liquid sheet is held to a lip by its own surface tension, and it lets go at the one speed that tension cannot carry — the speed of waves along the sheet — whatever the lip's radius.

misconceptions · Coanda
The same wavelength drawn as rolls and as hexagons. Plan views of a convecting layer with one critical wavelength, drawn from the amplitude equations' two stable states. On the left, rolls: a single set of parallel bands, rising fluid along one set of lines and sinking along the next. On the right, hexagons: three sets of rolls at 120° to each other with equal amplitudes, whose sum has its maxima on a triangular lattice with spacing 2/√3 of the wavelength, each maximum at the centre of a hexagonal cell. At ε = 0.0250, inside the window, both are stable: rolls with amplitude 0.158 and hexagons with 0.081 in each of their three rolls. A hexagon is not a different kind of cell; it is three roll patterns that the quadratic term lets reinforce one another.

Hexagons remember how the heat was turned up

A layer heated from below convects in rolls, unless its top and bottom are not mirror images of each other. Then three sets of rolls at 120° can feed one another through a term the symmetry used to forbid, hexagonal cells appear before the layer is formally unstable, and there is a range of heating in which rolls and hexagons are both stable — so the pattern a layer shows depends on whether the heat was turned up or down to get there.

turbulence · Convection
A force that depends on the molecular scale only through its logarithm. The force per unit length needed to move a 30° contact line of water at 1 mm/s, out to 1 mm, against the slip length on a logarithmic axis, from a picometre to a tenth of a millimetre. Each tenfold change in the slip length moves the force by the same fixed amount, so eight decades of the most uncertain length in the problem change the answer by a factor of about twenty — and at zero slip length the line keeps rising without end. The dashed curve takes the exact wedge's angle factor with a sharp cutoff; the solid one the thin-film wedge with Navier slip.

The drop a no-slip wall would never let spread

Liquid touching a solid moves with it, and nearly everywhere that is as close to exact as anything in fluid mechanics. At the edge of a spreading drop it cannot be: the stress in the corner rises as one over the distance from the edge, and the force needed to move the edge is infinite. Something slips over a nanometre, and because the answer depends on that length only through its logarithm, a drop spreads at almost the same rate whatever the something is.

misconceptions · The no-slip condition
A drop fed into a tube, to scale, up to the largest one it can hold. Six members of the family of static drops a tube of radius half a capillary length holds, drawn to scale and hung from the rim, with their volumes in cubic capillary lengths. The drop grows from a shallow cap through a hemisphere to a bulb with a neck. The last is the fold: no static drop on this tube holds more, and it holds 76 per cent of what Tate's law says the tube can carry.

The drop falls at a fold

Tate's law says a drop leaves a tube when its weight equals the tension round the rim. No force balance decides it. A tube holds a family of static drops, the family has a largest member, and the drop falls because there is no static shape with more liquid in it — which Tate's balance overestimates by a quarter on a millimetre tube and underestimates on a wide one.

regimes · Bond
Four tubes to scale, and the level Jurin's law gives each. Water rising in tubes of radius half a capillary length to four, drawn to one scale, with the level of the liquid far outside the tubes at the bottom. The red line in each tube is Jurin's height, 2ℓ²/R. In the narrow tube the surface is nearly flat and sits on it. In the wide ones the liquid gathers in a rim at the wall, the centre hardly rises, and Jurin's level runs through the middle of a surface that is nowhere near it — while still being its exact average.

A law that is exact as an average

Jurin's law gives the height water climbs in a tube as twice the square of the capillary length over the radius. As a statement about the height it is an approximation for narrow tubes. As a statement about the mean height of everything lifted it is exact for every tube — and a wide tube shows what the average was hiding: a rim of water at the wall and almost nothing in the middle.

regimes · Bond
One rim, one drop, every angle in the band. Water on a disc the size of a US cent, 19.1 mm across, pinned at its rim. The faint outlines are the drop at apparent angles of 60°, 90°, 120° and 150°; the dark one is the drop at the angle set, 120°, holding 1.13 mL. The rim stays put while the angle climbs, and every shape is an equilibrium: 0.52 mL at 60°, 1.44 mL at 150°. They are flattened by gravity into puddles with rounded edges, not spherical caps.

An edge holds any angle it is given

A liquid's contact angle is taught as a property of the liquid and the solid. On a smooth face it is. On a sharp edge the line stops, the angle is free to take any value in a band as wide as the edge is sharp, and that freedom is how a coin carries a dome of water and a glass stands full above its brim.

misconceptions · Coanda
The first three ways a drop can ring. A drop's first three modes of oscillation, each drawn at the two ends of its swing: the shaded outline and the red one are half a period apart. The fundamental, l = 2, alternates between a lemon and a lentil. The next two ring at 1.94 and 3.00 times its pitch, with three and four lobes. The swings are drawn at a fifth of the radius so they can be seen; the frequencies belong to swings much smaller than that.

A drop rings like a bell

Disturb a drop and it swings between a lemon and a lentil at a pitch set by its surface tension and its size, and it keeps swinging for dozens of cycles because water is nearly frictionless at that scale. The usual story has a falling raindrop's wake ringing it. The wake strikes several times too fast for the note the drop plays.

regimes · Drop shape
The drip spacing is set by the depth of the layer. The spacing of the fastest-growing wave, in units of 2π capillary lengths, against the depth of the hanging layer in capillary lengths, for water, glycerol and honey. A thin film of any of them drips at √2. Deep water drips at √3. Deep glycerol and honey keep growing past √3, their fastest wave as long as the layer is deep, because viscosity slows short waves more than long ones.

How far apart a ceiling drips

A layer of liquid hanging from a ceiling is heavy fluid over light, and every ripple on it longer than about seventeen millimetres grows. Which ripple grows fastest, and so how far apart the drips form, is usually given as one number. It is at least three, and what chooses between them is not the liquid's surface tension but the depth of the layer.

turbulence · Instability
Whether a sloping ceiling drips in place is one ray's growth. How fast a disturbance grows as seen by an observer moving along the ceiling at speed v, for four speeds at which the film carries its disturbances downhill, in the film's own units. On a flat ceiling (V = 0) the growth peaks at a quarter for the observer standing still and falls to zero for one running at ±1.622. Tilting the ceiling slides the whole curve downhill. While the observer at the point disturbed, v = 0, still sees growth, the ceiling drips where the disturbance began; at V = 1.622 that observer sees none, and above it the disturbance grows only while it is carried away.

A sloping ceiling drips downhill, or not at all

A film hanging from a level ceiling drips where its ripples form. Tilt the ceiling and the film flows downhill, carrying its ripples with it, and at some slope they are carried away faster than they spread and the ceiling stops dripping in place. That slope is set by one number, 1.622 — the speed at which a level ceiling's disturbance spreads — and for water it is tiny: a degree for a tenth of a millimetre of film, six for half a millimetre. Past it the ripples still grow, and still drip, but downhill, at a distance that grows with the slope: a ceiling shorter than that delivers its water to the edge.

turbulence · Instability
What a tilted pane holds is a difference of two cosines. The largest ridge a tilted plate holds, as a cross-section in square capillary lengths, against the tilt, for clean glass (advancing 30°, receding 10°), a plastic (90°, 70°) and a water-repellent coating (115°, 95°): the force balance (cos θᵣ − cos θₐ) ÷ sin α, and, as points, the areas of drops shot from Young–Laplace, which do not use it. Clean glass holds least, not because water sticks to it less but because on a surface it wets well the two cosines are nearly equal.

The force a contact line holds is a range

Capillary rise and the drop on a window are usually drawn with one contact angle, and a contact line with one angle makes a force that is a single number. A real contact line pins, and stops anywhere between a receding and an advancing angle. The force it holds is then a range, as static friction is, and its width is surface tension times the difference of two cosines. A tube holds its column at any height in the range, so which way the meniscus last moved matters more than how patchy the wall is — and a tilted pane holds a drop only as large as that difference allows.

regimes · Bond
Below the capillary length, the coat is set by the fibre, not the bath. The coat's thickness in units of ℓ_c Ca^(2/3) against the fibre's radius in capillary lengths, on logarithmic axes: the dynamic meniscus's 1.3376 over the curvature the static meniscus asks of it, 1/b + Z/ℓ_c². Thin fibres take Quéré's 1.3376 b Ca^(2/3), set by their own radius; thick ones take Landau–Levich's 0.9458 ℓ_c Ca^(2/3). The two laws cross at b = 0.71 ℓ_c, where the coat is 0.61 of either; at b = 0.1 ℓ_c it is 0.137 of what the plate's law would give.

A thin fibre coats by its own radius, and beads by it

A plate drawn out of a bath carries a film set by the capillary length, the size at which surface tension and gravity balance. A fibre thinner than that length carries a film set by its own radius instead, often a tenth of what the plate's law promises — and the same radius then decides how quickly that film gathers into beads. The faster the fibre is drawn, the thicker its coat and the shorter the length of it that comes out smooth.

viscous · Coating
Past its threshold a ridge slides at a speed its angles set. The steady speed of a ridge of liquid one square capillary length in cross-section, as a capillary number, against the plate's tilt, on three surfaces. Below each surface's threshold it is stuck. Past it the speed rises from zero, linearly at first, as far as the tilt allows. On clean glass the curve barely exists: between its threshold and the speed at which its uphill contact line fails there is a sliver of tilt, and a ridge pushed past that cannot slide steadily with a clean trailing edge.

A sliding drop is held harder the faster it goes

A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.

regimes · Bond
An edge is worth its sharpness against the capillary length. The extra height a rounded edge holds over a flat plate, as a fraction of what a sharp edge holds, against the rounding radius in capillary lengths, for Young angles of 30°, 60° and 90°. An edge rounded to a thirtieth of a capillary length, about a tenth of a millimetre for water, keeps about ninety-five per cent. One rounded to a third of a millimetre keeps between eight and nine tenths; one rounded to a whole capillary length, about a third; and past that the worth falls as the inverse of the radius.

A rounded edge spills before its line goes round

Gibbs's band says a sharp edge lets a liquid stand at any angle across a range as wide as the edge's turn. No real edge is sharp, and on a rounded one the line does not stop; it slides round the curve, meeting it at the Young angle everywhere. The band survives the sliding. What the rounding costs is height, because the line drops as it goes round, and past a point the drop outweighs the steeper angle and the liquid spills before the line has reached the far face. An edge is worth its sharpness measured against the capillary length, and nothing smaller.

misconceptions · Coanda
Dissolved gas takes height from the largest nuclei first. The tallest crown a siphon runs over, against the radius of its largest nucleus at the reservoir, when a nucleus at the crown must neither break the water at once nor grow to break it by diffusion, for water at 0, 10, 30, 60 and 100 per cent of saturation. Fully degassed water gives the static limit. For a one-micron nucleus, gas below about a fifth of saturation changes nothing — 14.41 m against 14.41 — and saturated water brings it to 10.7 m. A five-micron nucleus in saturated water breaks the siphon at 2.4 m.

A crown dissolves its nuclei or breaks on them, and fast

A siphon of degassed water runs until its crown's tension reaches the breaking threshold of its largest nucleus. A nucleus lodged at the crown does not stay the size it arrived: it gains or loses gas by diffusion, and across a micron diffusion takes milliseconds, so the crown gives its verdict almost at once. Every stable nucleus loses gas unless the water holds more than half the crown's tension, and past a knee in gas content, dissolved air takes height from a siphon's crown that no amount of further degassing gives back.

misconceptions · Siphon

A crevice keeps the nucleus a free bubble loses

A free bubble at a siphon's crown dissolves in milliseconds, so it cannot be what breaks a siphon that has run for an hour. A pocket of gas in a crack of the hose wall can be, because its meniscus is curved by the wall and need not dissolve. Followed through its equilibria, the pocket escapes at a tension set almost entirely by the crack's mouth. What the wall's wettability decides is slower and more consequential: whether the crack fills, or keeps drawing gas in until the siphon breaks.

misconceptions · Siphon

Viscosity lets a jet break, later and into bigger drops

A thread of honey falls for metres before it breaks, and a thread of water for centimetres, which suggests that viscosity holds a jet together. It does not: it cannot stop any ripple longer than the jet's circumference from growing. It slows them, the short ones most, so the ripple that wins is longer, it takes the viscous time rather than the capillary one to win, and each drop it makes is bigger. The wavelength grows as the square root of the Ohnesorge number and the drop as its sixth root.

regimes · Atomisation

The fastest finger is set by the gap and one number

Push air into oil between two glass plates and the interface breaks into fingers. The averaged law of the cell makes the instability exact in its linear stage: every wavelength is driven in proportion to its wavenumber, surface tension holds back the short ones as the cube, and the fastest finger is π gap widths divided by the square root of a capillary number. A narrow channel stays flat; a wide one chooses how many fingers to make; and a growing bubble of air makes more of them the larger it gets.

inviscid · Hele-shaw

The air shortens a jet's fastest ripple, and the drops follow

A jet in a vacuum breaks into drops nearly twice its own width, whatever its speed. A jet in air does not, and the reason is a pressure the air puts on its surface: flowing over a rippled jet it is faster over the crests and its pressure lower there, which pulls them further out. That pull lets ripples shorter than the jet's circumference grow, shortens the fastest one, shrinks the drops, and puts a ceiling on how long a fast jet can be — at the gas Weber number where the measured break-up regimes change.

regimes · Atomisation

The warm side pulls a bubble with no force on it

A bubble in a liquid whose temperature varies from place to place moves towards the warm side, with no gravity and nothing pushing it. The surface tension is lower where the liquid is warmer, the surface is pulled towards the cold pole, and the bubble goes the other way. Young, Goldstein and Block's speed comes out of four interface conditions and one more: that the total force on the bubble is zero. That one condition removes the point force a sinking or rising body always carries, so the bubble's disturbance dies a hundred times faster with distance, and the radius at which it balances its own buoyancy has no viscosity in it.

viscous · Mobile interface

The meniscus slows the finger and hardly moves it

Air pushing oil through a narrow gap fingers at a wavelength the gap and one number set, on the assumption that surface tension acts only on the interface's curve in the plane. The interface is really a meniscus across the gap, leaving a film behind, and Park and Homsy's correction for it does two things that nearly cancel in the wavelength: it cuts the tension to π/4 and adds a drag that grows with speed. At bench speeds the fastest finger barely moves; it grows a quarter more slowly, and a channel goes unstable at four-fifths of the speed.

inviscid · Hele-shaw

A bowed meniscus keeps most of its slip until the groove floods

The slip lengths of a striped superhydrophobic surface are computed with flat gas surfaces. Press the liquid against the texture and every meniscus bows into its groove as an arc pinned at the solid's edges, and the slip falls. It falls by less than the obvious worry says: at the pressure where a groove wall advancing at 120° lets the liquid in, a surface four-fifths gas still keeps 88 per cent of its slip, and even at a 150° wall's flood three-quarters remains. A striped surface does not lose its slip gradually under pressure. It keeps most of it, and then loses all of it when the groove floods.

kinematics · Boundary conditions

Named alongside it

The objects these essays reach for when they reach for this one.

Model limitYoung laplaceDropContact angleCapillary lengthThresholdCapillary numberMeasurementBond numberCavitationMisconceptionViscosity

All concepts