Surface tension — where it appears
Named by 31 essays across 7 fields — each of them below, with the objects they name alongside it.
Where a jet stops being a jet
A tap makes drops a few centimetres down, a garden hose makes a stream that carries, a sprayer makes a mist and a diesel injector makes fog. Same liquid, same mechanism, four regimes — and the number that separates them is not the jet's inertia but the surrounding air's.
The size a drop is allowed
The Bond number sets a drop's weight against the force its own skin can supply, and it is one when they are equal. By then the drop is a bun — it is a per cent from being a ball at Bond number 0.0079, which is a water drop half a millimetre across.
The drop that is not a tear
A falling raindrop is flattened along the direction it is going, by the pressure of the air passing it rather than by its own weight, and the group that decides is the Weber number. The teardrop of every illustration has the wrong symmetry entirely — there is no up in the problem it is drawn for.
What a plate takes with it
Pull a plate out of a bath and it comes out wet. How wet is not set by the plate, the bath or how much liquid there is, but by a competition in a region a fraction of a millimetre long that nobody looking at the plate can see — and the film goes as the two-thirds power of the speed, never as the first.
The number that cannot break a drop
The capillary number sets the stress that stretches a drop against the stress that holds it round, and it predicts the deformation beautifully. It cannot predict the breakup, because above a viscosity ratio of about four a drop in simple shear cannot be broken at any shear rate — and the theory that says the ratio hardly matters is the same theory that gets the deformation right.
A threshold that is also a duration
The cavitation number treats inception as a pressure: below it the liquid tears, above it does not. A five-micron bubble asked to grow in 0.3 microseconds needs 43 bar of tension and the same bubble given a hundred needs 1.05, because it has to make a journey and not merely respond.
Where a liquid does pull
A fluid cannot pull, and the essays that settle what suction is are right about every gas and every liquid with a free surface near it. A liquid with nothing in it to boil on is another matter. Every tree taller than ten metres depends on the difference, and the floor under it is set by the size of a pore rather than by the vapour pressure.
A breaking strength that is the size of a flaw
Water can be stretched, and how far is a measurement people have made for a century and a half with instruments that agree with one another and not with the theory. Spinning a tube puts the stretch where no gas can reach it, sealing one caps the stretch at water's density maximum, and every measured number turns out to name the size of the worst cavity in the sample.
The air that breaks a siphon nothing else can
A running siphon's heights cannot break it, and its friction only postpones the moment it is most exposed. What does break a siphon that has run for a day is the air dissolved in its water, which the crown's low pressure leaves the water carrying far more of than it can hold — and which gathers only once the flow is too slow to carry a bubble away.
Twice as slippery along as across
A surface of alternating gas and solid stripes lets a liquid slip, and a flow far above it sees one number in place of the pattern — but the number depends on which way the flow goes. Along the stripes it is Philip's logarithm; across them it is exactly half, for a reason that takes one substitution to show. And the logarithm means that the slip is bought by the pattern's period rather than by how much of it is gas.
The teapot effect is a tension, not a pressure
A slow pour runs back under a spout and down its outside, and the name it is usually given is the Coandă effect. The Coandă effect borrows the ambient pressure, and a liquid in air has none to borrow. A liquid sheet is held to a lip by its own surface tension, and it lets go at the one speed that tension cannot carry — the speed of waves along the sheet — whatever the lip's radius.
Hexagons remember how the heat was turned up
A layer heated from below convects in rolls, unless its top and bottom are not mirror images of each other. Then three sets of rolls at 120° can feed one another through a term the symmetry used to forbid, hexagonal cells appear before the layer is formally unstable, and there is a range of heating in which rolls and hexagons are both stable — so the pattern a layer shows depends on whether the heat was turned up or down to get there.
The drop a no-slip wall would never let spread
Liquid touching a solid moves with it, and nearly everywhere that is as close to exact as anything in fluid mechanics. At the edge of a spreading drop it cannot be: the stress in the corner rises as one over the distance from the edge, and the force needed to move the edge is infinite. Something slips over a nanometre, and because the answer depends on that length only through its logarithm, a drop spreads at almost the same rate whatever the something is.
The drop falls at a fold
Tate's law says a drop leaves a tube when its weight equals the tension round the rim. No force balance decides it. A tube holds a family of static drops, the family has a largest member, and the drop falls because there is no static shape with more liquid in it — which Tate's balance overestimates by a quarter on a millimetre tube and underestimates on a wide one.
A law that is exact as an average
Jurin's law gives the height water climbs in a tube as twice the square of the capillary length over the radius. As a statement about the height it is an approximation for narrow tubes. As a statement about the mean height of everything lifted it is exact for every tube — and a wide tube shows what the average was hiding: a rim of water at the wall and almost nothing in the middle.
An edge holds any angle it is given
A liquid's contact angle is taught as a property of the liquid and the solid. On a smooth face it is. On a sharp edge the line stops, the angle is free to take any value in a band as wide as the edge is sharp, and that freedom is how a coin carries a dome of water and a glass stands full above its brim.
A drop rings like a bell
Disturb a drop and it swings between a lemon and a lentil at a pitch set by its surface tension and its size, and it keeps swinging for dozens of cycles because water is nearly frictionless at that scale. The usual story has a falling raindrop's wake ringing it. The wake strikes several times too fast for the note the drop plays.
How far apart a ceiling drips
A layer of liquid hanging from a ceiling is heavy fluid over light, and every ripple on it longer than about seventeen millimetres grows. Which ripple grows fastest, and so how far apart the drips form, is usually given as one number. It is at least three, and what chooses between them is not the liquid's surface tension but the depth of the layer.
A sloping ceiling drips downhill, or not at all
A film hanging from a level ceiling drips where its ripples form. Tilt the ceiling and the film flows downhill, carrying its ripples with it, and at some slope they are carried away faster than they spread and the ceiling stops dripping in place. That slope is set by one number, 1.622 — the speed at which a level ceiling's disturbance spreads — and for water it is tiny: a degree for a tenth of a millimetre of film, six for half a millimetre. Past it the ripples still grow, and still drip, but downhill, at a distance that grows with the slope: a ceiling shorter than that delivers its water to the edge.
The force a contact line holds is a range
Capillary rise and the drop on a window are usually drawn with one contact angle, and a contact line with one angle makes a force that is a single number. A real contact line pins, and stops anywhere between a receding and an advancing angle. The force it holds is then a range, as static friction is, and its width is surface tension times the difference of two cosines. A tube holds its column at any height in the range, so which way the meniscus last moved matters more than how patchy the wall is — and a tilted pane holds a drop only as large as that difference allows.
A thin fibre coats by its own radius, and beads by it
A plate drawn out of a bath carries a film set by the capillary length, the size at which surface tension and gravity balance. A fibre thinner than that length carries a film set by its own radius instead, often a tenth of what the plate's law promises — and the same radius then decides how quickly that film gathers into beads. The faster the fibre is drawn, the thicker its coat and the shorter the length of it that comes out smooth.
A sliding drop is held harder the faster it goes
A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.
A rounded edge spills before its line goes round
Gibbs's band says a sharp edge lets a liquid stand at any angle across a range as wide as the edge's turn. No real edge is sharp, and on a rounded one the line does not stop; it slides round the curve, meeting it at the Young angle everywhere. The band survives the sliding. What the rounding costs is height, because the line drops as it goes round, and past a point the drop outweighs the steeper angle and the liquid spills before the line has reached the far face. An edge is worth its sharpness measured against the capillary length, and nothing smaller.
A crown dissolves its nuclei or breaks on them, and fast
A siphon of degassed water runs until its crown's tension reaches the breaking threshold of its largest nucleus. A nucleus lodged at the crown does not stay the size it arrived: it gains or loses gas by diffusion, and across a micron diffusion takes milliseconds, so the crown gives its verdict almost at once. Every stable nucleus loses gas unless the water holds more than half the crown's tension, and past a knee in gas content, dissolved air takes height from a siphon's crown that no amount of further degassing gives back.
A crevice keeps the nucleus a free bubble loses
A free bubble at a siphon's crown dissolves in milliseconds, so it cannot be what breaks a siphon that has run for an hour. A pocket of gas in a crack of the hose wall can be, because its meniscus is curved by the wall and need not dissolve. Followed through its equilibria, the pocket escapes at a tension set almost entirely by the crack's mouth. What the wall's wettability decides is slower and more consequential: whether the crack fills, or keeps drawing gas in until the siphon breaks.
Viscosity lets a jet break, later and into bigger drops
A thread of honey falls for metres before it breaks, and a thread of water for centimetres, which suggests that viscosity holds a jet together. It does not: it cannot stop any ripple longer than the jet's circumference from growing. It slows them, the short ones most, so the ripple that wins is longer, it takes the viscous time rather than the capillary one to win, and each drop it makes is bigger. The wavelength grows as the square root of the Ohnesorge number and the drop as its sixth root.
The fastest finger is set by the gap and one number
Push air into oil between two glass plates and the interface breaks into fingers. The averaged law of the cell makes the instability exact in its linear stage: every wavelength is driven in proportion to its wavenumber, surface tension holds back the short ones as the cube, and the fastest finger is π gap widths divided by the square root of a capillary number. A narrow channel stays flat; a wide one chooses how many fingers to make; and a growing bubble of air makes more of them the larger it gets.
The air shortens a jet's fastest ripple, and the drops follow
A jet in a vacuum breaks into drops nearly twice its own width, whatever its speed. A jet in air does not, and the reason is a pressure the air puts on its surface: flowing over a rippled jet it is faster over the crests and its pressure lower there, which pulls them further out. That pull lets ripples shorter than the jet's circumference grow, shortens the fastest one, shrinks the drops, and puts a ceiling on how long a fast jet can be — at the gas Weber number where the measured break-up regimes change.
The warm side pulls a bubble with no force on it
A bubble in a liquid whose temperature varies from place to place moves towards the warm side, with no gravity and nothing pushing it. The surface tension is lower where the liquid is warmer, the surface is pulled towards the cold pole, and the bubble goes the other way. Young, Goldstein and Block's speed comes out of four interface conditions and one more: that the total force on the bubble is zero. That one condition removes the point force a sinking or rising body always carries, so the bubble's disturbance dies a hundred times faster with distance, and the radius at which it balances its own buoyancy has no viscosity in it.
The meniscus slows the finger and hardly moves it
Air pushing oil through a narrow gap fingers at a wavelength the gap and one number set, on the assumption that surface tension acts only on the interface's curve in the plane. The interface is really a meniscus across the gap, leaving a film behind, and Park and Homsy's correction for it does two things that nearly cancel in the wavelength: it cuts the tension to π/4 and adds a drag that grows with speed. At bench speeds the fastest finger barely moves; it grows a quarter more slowly, and a channel goes unstable at four-fifths of the speed.
A bowed meniscus keeps most of its slip until the groove floods
The slip lengths of a striped superhydrophobic surface are computed with flat gas surfaces. Press the liquid against the texture and every meniscus bows into its groove as an arc pinned at the solid's edges, and the slip falls. It falls by less than the obvious worry says: at the pressure where a groove wall advancing at 120° lets the liquid in, a surface four-fifths gas still keeps 88 per cent of its slip, and even at a 150° wall's flood three-quarters remains. A striped surface does not lose its slip gradually under pressure. It keeps most of it, and then loses all of it when the groove floods.
Named alongside it
The objects these essays reach for when they reach for this one.
Model limitYoung laplaceDropContact angleCapillary lengthThresholdCapillary numberMeasurementBond numberCavitationMisconceptionViscosity