Concept

Drop — where it appears

A body of liquid held together by its own surface, whose shape is set by the balance between tension and whatever is pushing on it. Gravity flattens it through the Bond number and a passing airflow flattens it through the Weber number, and the two mechanisms are unrelated.

Named by 11 essays across 2 fields — each of them below, with the objects they name alongside it.

How big before gravity shows. A drop's height over its width against the Bond number, which is the ratio of its weight to the force its own skin can supply. The number is one where those two are equal, and by then the drop is a bun: it is one per cent from a ball at Bo = 0.0079, five per cent at 0.054 and ten at 0.13. Every one of those is below one, and the first is below it by a factor of a hundred and twenty-six.

The size a drop is allowed

The Bond number sets a drop's weight against the force its own skin can supply, and it is one when they are equal. By then the drop is a bun — it is a per cent from being a ball at Bond number 0.0079, which is a water drop half a millimetre across.

regimes · Bond
A falling drop is a bun, not a tear. The shape of a drop pressed on by the air it is falling through, computed by matching the Legendre component of a sphere's own potential-flow pressure distribution against the change in curvature it produces. The result is oblate — flattened along the direction of travel — because the pressure is high at the poles and low round the equator. The teardrop of every illustration has the wrong symmetry entirely: a drop in free fall has no up, and one at terminal speed is being pressed on from in front.

The drop that is not a tear

A falling raindrop is flattened along the direction it is going, by the pressure of the air passing it rather than by its own weight, and the group that decides is the Weber number. The teardrop of every illustration has the wrong symmetry entirely — there is no up in the problem it is drawn for.

regimes · Drop shape
Two-thirds to one, and nothing outside it. The drag on a spherical drop as a fraction of Stokes' drag on a rigid sphere of the same size, against the ratio of the viscosities. It runs from exactly two-thirds for a clean gas bubble to exactly one for a rigid particle and takes no value outside that range, however light or heavy the drop is — the formula has no density in it anywhere. A drop of water in air and a drop of mercury in water sit at opposite ends of it.

The surface that moves with the flow

A clean gas bubble feels two-thirds of the drag a rigid sphere of the same size would, and the formula has no density in it anywhere. What buys the third is that the bubble's surface is free to move — and real bubbles in ordinary water do not get it, for a reason that is a millionth of a per cent of the water by mass.

viscous · Mobile interface
Drop deformation in simple shear, against the capillary number. The shape model's steady deformation for six viscosity ratios. Every curve is linear in the capillary number at small Ca — which is Taylor's result — and every one of them saturates, at 5/2(2λ+3), because the shear's own rotation turns the drop out of the stretching direction. A drop in simple shear cannot be deformed beyond that however hard it is sheared.

The number that cannot break a drop

The capillary number sets the stress that stretches a drop against the stress that holds it round, and it predicts the deformation beautifully. It cannot predict the breakup, because above a viscosity ratio of about four a drop in simple shear cannot be broken at any shear rate — and the theory that says the ratio hardly matters is the same theory that gets the deformation right.

regimes · Capillary
A drop fed into a tube, to scale, up to the largest one it can hold. Six members of the family of static drops a tube of radius half a capillary length holds, drawn to scale and hung from the rim, with their volumes in cubic capillary lengths. The drop grows from a shallow cap through a hemisphere to a bulb with a neck. The last is the fold: no static drop on this tube holds more, and it holds 76 per cent of what Tate's law says the tube can carry.

The drop falls at a fold

Tate's law says a drop leaves a tube when its weight equals the tension round the rim. No force balance decides it. A tube holds a family of static drops, the family has a largest member, and the drop falls because there is no static shape with more liquid in it — which Tate's balance overestimates by a quarter on a millimetre tube and underestimates on a wide one.

regimes · Bond
The first three ways a drop can ring. A drop's first three modes of oscillation, each drawn at the two ends of its swing: the shaded outline and the red one are half a period apart. The fundamental, l = 2, alternates between a lemon and a lentil. The next two ring at 1.94 and 3.00 times its pitch, with three and four lobes. The swings are drawn at a fifth of the radius so they can be seen; the frequencies belong to swings much smaller than that.

A drop rings like a bell

Disturb a drop and it swings between a lemon and a lentil at a pitch set by its surface tension and its size, and it keeps swinging for dozens of cycles because water is nearly frictionless at that scale. The usual story has a falling raindrop's wake ringing it. The wake strikes several times too fast for the note the drop plays.

regimes · Drop shape
What a tilted pane holds is a difference of two cosines. The largest ridge a tilted plate holds, as a cross-section in square capillary lengths, against the tilt, for clean glass (advancing 30°, receding 10°), a plastic (90°, 70°) and a water-repellent coating (115°, 95°): the force balance (cos θᵣ − cos θₐ) ÷ sin α, and, as points, the areas of drops shot from Young–Laplace, which do not use it. Clean glass holds least, not because water sticks to it less but because on a surface it wets well the two cosines are nearly equal.

The force a contact line holds is a range

Capillary rise and the drop on a window are usually drawn with one contact angle, and a contact line with one angle makes a force that is a single number. A real contact line pins, and stops anywhere between a receding and an advancing angle. The force it holds is then a range, as static friction is, and its width is surface tension times the difference of two cosines. A tube holds its column at any height in the range, so which way the meniscus last moved matters more than how patchy the wall is — and a tilted pane holds a drop only as large as that difference allows.

regimes · Bond
Past its threshold a ridge slides at a speed its angles set. The steady speed of a ridge of liquid one square capillary length in cross-section, as a capillary number, against the plate's tilt, on three surfaces. Below each surface's threshold it is stuck. Past it the speed rises from zero, linearly at first, as far as the tilt allows. On clean glass the curve barely exists: between its threshold and the speed at which its uphill contact line fails there is a sliver of tilt, and a ridge pushed past that cannot slide steadily with a clean trailing edge.

A sliding drop is held harder the faster it goes

A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.

regimes · Bond
Viscosity slows every ripple, and the short ones most. The growth rate of a varicose ripple on a liquid jet against its wavenumber times the jet's radius, at Ohnesorge numbers of 0, 0.1, 1 and 10, in units of the capillary time. Every ripple longer than the circumference grows. Viscosity damps each one in proportion to the square of its wavenumber, so the short ones lose most: the fastest moves from ka = 0.697 inviscid to 0.344 at Oh = 1 and 0.123 at Oh = 10, and its rate falls from 0.343 to 0.0114.

Viscosity lets a jet break, later and into bigger drops

A thread of honey falls for metres before it breaks, and a thread of water for centimetres, which suggests that viscosity holds a jet together. It does not: it cannot stop any ripple longer than the jet's circumference from growing. It slows them, the short ones most, so the ripple that wins is longer, it takes the viscous time rather than the capillary one to win, and each drop it makes is bigger. The wavelength grows as the square root of the Ohnesorge number and the drop as its sixth root.

regimes · Atomisation
The air pulls on the crests, and short ripples start to grow. The growth rate of a ripple on an inviscid jet against its wavenumber times the radius, at gas Weber numbers of 0, 0.4, 2, 6 and 13 on the diameter. The air flowing over a rippled jet is faster over the crests and its pressure lower there, which pulls them further out. Without it nothing shorter than the circumference grows; at a gas Weber number of 2 ripples up to ka = 1.45 grow, at 13 up to 6.19, and the fastest moves with them.

The air shortens a jet's fastest ripple, and the drops follow

A jet in a vacuum breaks into drops nearly twice its own width, whatever its speed. A jet in air does not, and the reason is a pressure the air puts on its surface: flowing over a rippled jet it is faster over the crests and its pressure lower there, which pulls them further out. That pull lets ripples shorter than the jet's circumference grow, shortens the fastest one, shrinks the drops, and puts a ceiling on how long a fast jet can be — at the gas Weber number where the measured break-up regimes change.

regimes · Atomisation
Below 9.8 µm in silicone oil, a gradient of a degree per millimetre outruns gravity. The speed of a clean air bubble in 10 cSt silicone oil against its radius, on logarithmic axes: migrating in a gradient of 1 K/mm, which grows in proportion to the radius, and rising under its weight, which grows with its square. They cross at 9.81 µm and 31 µm/s. The crossing radius, 3|dσ/dT|G/(2ρg), has no viscosity in it: both speeds are set against the same viscous drag.

The warm side pulls a bubble with no force on it

A bubble in a liquid whose temperature varies from place to place moves towards the warm side, with no gravity and nothing pushing it. The surface tension is lower where the liquid is warmer, the surface is pulled towards the cold pole, and the bubble goes the other way. Young, Goldstein and Block's speed comes out of four interface conditions and one more: that the total force on the bubble is zero. That one condition removes the point force a sinking or rising body always carries, so the bubble's disturbance dies a hundred times faster with distance, and the radius at which it balances its own buoyancy has no viscosity in it.

viscous · Mobile interface

Named alongside it

The objects these essays reach for when they reach for this one.

Surface tensionModel limitThresholdYoung laplaceBond numberCapillary lengthContact angleAtomisationBubbleCapillary numberCreeping flowDimensionless

All concepts