Contact angle — where it appears
Named by 9 essays across 3 fields — each of them below, with the objects they name alongside it.
The size a drop is allowed
The Bond number sets a drop's weight against the force its own skin can supply, and it is one when they are equal. By then the drop is a bun — it is a per cent from being a ball at Bond number 0.0079, which is a water drop half a millimetre across.
The drop a no-slip wall would never let spread
Liquid touching a solid moves with it, and nearly everywhere that is as close to exact as anything in fluid mechanics. At the edge of a spreading drop it cannot be: the stress in the corner rises as one over the distance from the edge, and the force needed to move the edge is infinite. Something slips over a nanometre, and because the answer depends on that length only through its logarithm, a drop spreads at almost the same rate whatever the something is.
A law that is exact as an average
Jurin's law gives the height water climbs in a tube as twice the square of the capillary length over the radius. As a statement about the height it is an approximation for narrow tubes. As a statement about the mean height of everything lifted it is exact for every tube — and a wide tube shows what the average was hiding: a rim of water at the wall and almost nothing in the middle.
An edge holds any angle it is given
A liquid's contact angle is taught as a property of the liquid and the solid. On a smooth face it is. On a sharp edge the line stops, the angle is free to take any value in a band as wide as the edge is sharp, and that freedom is how a coin carries a dome of water and a glass stands full above its brim.
The force a contact line holds is a range
Capillary rise and the drop on a window are usually drawn with one contact angle, and a contact line with one angle makes a force that is a single number. A real contact line pins, and stops anywhere between a receding and an advancing angle. The force it holds is then a range, as static friction is, and its width is surface tension times the difference of two cosines. A tube holds its column at any height in the range, so which way the meniscus last moved matters more than how patchy the wall is — and a tilted pane holds a drop only as large as that difference allows.
A sliding drop is held harder the faster it goes
A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.
A rounded edge spills before its line goes round
Gibbs's band says a sharp edge lets a liquid stand at any angle across a range as wide as the edge's turn. No real edge is sharp, and on a rounded one the line does not stop; it slides round the curve, meeting it at the Young angle everywhere. The band survives the sliding. What the rounding costs is height, because the line drops as it goes round, and past a point the drop outweighs the steeper angle and the liquid spills before the line has reached the far face. An edge is worth its sharpness measured against the capillary length, and nothing smaller.
A crevice keeps the nucleus a free bubble loses
A free bubble at a siphon's crown dissolves in milliseconds, so it cannot be what breaks a siphon that has run for an hour. A pocket of gas in a crack of the hose wall can be, because its meniscus is curved by the wall and need not dissolve. Followed through its equilibria, the pocket escapes at a tension set almost entirely by the crack's mouth. What the wall's wettability decides is slower and more consequential: whether the crack fills, or keeps drawing gas in until the siphon breaks.
A bowed meniscus keeps most of its slip until the groove floods
The slip lengths of a striped superhydrophobic surface are computed with flat gas surfaces. Press the liquid against the texture and every meniscus bows into its groove as an arc pinned at the solid's edges, and the slip falls. It falls by less than the obvious worry says: at the pressure where a groove wall advancing at 120° lets the liquid in, a surface four-fifths gas still keeps 88 per cent of its slip, and even at a 150° wall's flood three-quarters remains. A striped surface does not lose its slip gradually under pressure. It keeps most of it, and then loses all of it when the groove floods.
Named alongside it
The objects these essays reach for when they reach for this one.
Surface tensionModel limitYoung laplaceBond numberMeasurementThresholdCapillary lengthDropBoundary conditionCapillary numberCoandaFree surface