Concept

Capillary number — where it appears

The ratio of the viscous stress that deforms an interface to the interfacial stress that resists it. It decides how far a drop stretches in a shearing flow and how thick a film a withdrawn plate carries, and it cannot decide whether the drop breaks — that needs the viscosity ratio and the type of the flow as well.

Named by 7 essays across 4 fields — each of them below, with the objects they name alongside it.

Twice as fast is not twice as thick. The film a plate carries out of water, against the speed it is withdrawn at, both logarithmic. The slope is exactly two-thirds, so doubling the speed thickens the film by 58.7 per cent and never by more. The open marks are outside the range the derivation holds in — above a capillary number of about a hundredth the film is no longer thin against the capillary length, and the measured thickness leaves this line.

What a plate takes with it

Pull a plate out of a bath and it comes out wet. How wet is not set by the plate, the bath or how much liquid there is, but by a competition in a region a fraction of a millimetre long that nobody looking at the plate can see — and the film goes as the two-thirds power of the speed, never as the first.

viscous · Coating

Drop deformation in simple shear, against the capillary number. The shape model's steady deformation for six viscosity ratios. Every curve is linear in the capillary number at small Ca — which is Taylor's result — and every one of them saturates, at 5/2(2λ+3), because the shear's own rotation turns the drop out of the stretching direction. A drop in simple shear cannot be deformed beyond that however hard it is sheared.

The number that cannot break a drop

The capillary number sets the stress that stretches a drop against the stress that holds it round, and it predicts the deformation beautifully. It cannot predict the breakup, because above a viscosity ratio of about four a drop in simple shear cannot be broken at any shear rate — and the theory that says the ratio hardly matters is the same theory that gets the deformation right.

regimes · Capillary

A force that depends on the molecular scale only through its logarithm. The force per unit length needed to move a 30° contact line of water at 1 mm/s, out to 1 mm, against the slip length on a logarithmic axis, from a picometre to a tenth of a millimetre. Each tenfold change in the slip length moves the force by the same fixed amount, so eight decades of the most uncertain length in the problem change the answer by a factor of about twenty — and at zero slip length the line keeps rising without end. The dashed curve takes the exact wedge's angle factor with a sharp cutoff; the solid one the thin-film wedge with Navier slip.

The drop a no-slip wall would never let spread

Liquid touching a solid moves with it, and nearly everywhere that is as close to exact as anything in fluid mechanics. At the edge of a spreading drop it cannot be: the stress in the corner rises as one over the distance from the edge, and the force needed to move the edge is infinite. Something slips over a nanometre, and because the answer depends on that length only through its logarithm, a drop spreads at almost the same rate whatever the something is.

misconceptions · The no-slip condition

Below the capillary length, the coat is set by the fibre, not the bath. The coat's thickness in units of ℓ_c Ca^(2/3) against the fibre's radius in capillary lengths, on logarithmic axes: the dynamic meniscus's 1.3376 over the curvature the static meniscus asks of it, 1/b + Z/ℓ_c². Thin fibres take Quéré's 1.3376 b Ca^(2/3), set by their own radius; thick ones take Landau–Levich's 0.9458 ℓ_c Ca^(2/3). The two laws cross at b = 0.71 ℓ_c, where the coat is 0.61 of either; at b = 0.1 ℓ_c it is 0.137 of what the plate's law would give.

A thin fibre coats by its own radius, and beads by it

A plate drawn out of a bath carries a film set by the capillary length, the size at which surface tension and gravity balance. A fibre thinner than that length carries a film set by its own radius instead, often a tenth of what the plate's law promises — and the same radius then decides how quickly that film gathers into beads. The faster the fibre is drawn, the thicker its coat and the shorter the length of it that comes out smooth.

viscous · Coating

Past its threshold a ridge slides at a speed its angles set. The steady speed of a ridge of liquid one square capillary length in cross-section, as a capillary number, against the plate's tilt, on three surfaces. Below each surface's threshold it is stuck. Past it the speed rises from zero, linearly at first, as far as the tilt allows. On clean glass the curve barely exists: between its threshold and the speed at which its uphill contact line fails there is a sliver of tilt, and a ridge pushed past that cannot slide steadily with a clean trailing edge.

A sliding drop is held harder the faster it goes

A ridge of liquid on a tilted plate starts to slide when its weight beats the difference between its two contact angles' cosines. Once it moves, the angles move too: the front steepens and the back flattens, by a law set in the viscous corners at each edge. So the resistance rises with speed from exactly the static value, and a sliding drop has no kinetic friction lower than its static one — it stops at the tilt it started at. The back edge's angle falls to nothing at a finite speed, and past that no drop slides with a clean back.

regimes · Bond

Long waves grow, short ones are held flat, and one in between grows fastest. The growth rate of a ripple on the interface where air displaces oil in a Hele-Shaw cell, against its wavenumber, at displacement speeds of 0.5, 1 and 2 mm/s. The viscosity contrast drives every wavelength at a rate proportional to its wavenumber; surface tension holds back short ones as the cube. At 1 mm/s the cut-off is 0.245 per mm and the fastest wavenumber 0.141 per mm, a wavelength of 44.4 mm, growing at 0.0942 per second.

The fastest finger is set by the gap and one number

Push air into oil between two glass plates and the interface breaks into fingers. The averaged law of the cell makes the instability exact in its linear stage: every wavelength is driven in proportion to its wavenumber, surface tension holds back the short ones as the cube, and the fastest finger is π gap widths divided by the square root of a capillary number. A narrow channel stays flat; a wide one chooses how many fingers to make; and a growing bubble of air makes more of them the larger it gets.

inviscid · Hele-shaw

The meniscus shortens the fastest finger and its film lengthens it, and they cancel near Ca = 0.01. The fastest wavelength over the uncorrected π b/√Ca, against capillary number, with the in-plane tension reduced to π/4 alone, with the speed-dependent transverse jump alone, and with both. The reduced tension shortens every finger by √(π/4) = 0.8862; the film's jump lengthens it, more at higher capillary number; together they cancel at Ca = 0.0131, shorten the finger 5.8% at 10⁻⁴ and lengthen it 6.1% at 0.3.

The meniscus slows the finger and hardly moves it

Air pushing oil through a narrow gap fingers at a wavelength the gap and one number set, on the assumption that surface tension acts only on the interface's curve in the plane. The interface is really a meniscus across the gap, leaving a film behind, and Park and Homsy's correction for it does two things that nearly cancel in the wavelength: it cuts the tension to π/4 and adds a drag that grows with speed. At bench speeds the fastest finger barely moves; it grows a quarter more slowly, and a channel goes unstable at four-fifths of the speed.

inviscid · Hele-shaw

Named alongside it

The objects these essays reach for when they reach for this one.

Surface tension Model limit Viscosity Lubrication film Capillary length Coating Contact angle Darcy's law Drop Hele-shaw Instability Linear stability

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