Concept

Nucleation — where it appears

The first appearance of a new phase, such as a vapour cavity in a stretched liquid, which must pay the surface energy of a small nucleus before it can grow. Its threshold is set by the largest nucleus already present, or in a perfectly pure liquid by thermal fluctuations, which put water's at about −150 MPa.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

A threshold that is a curve, not a pressure. The tension a rectangular pulse has to reach to make a five-micron bubble run away, against how long the pulse lasts. At a tenth of a microsecond it takes forty bar; at a hundred microseconds it takes 1.05, which is within about one per cent of the static threshold. There is no such thing as the cavitation pressure of this bubble on its own.

A threshold that is also a duration

The cavitation number treats inception as a pressure: below it the liquid tears, above it does not. A five-micron bubble asked to grow in 0.3 microseconds needs 43 bar of tension and the same bubble given a hundred needs 1.05, because it has to make a journey and not merely respond.

applied · Cavitation

A tube 10 cm across, spun: the lowest pressure is on the axis. The absolute pressure along a water-filled tube spun about its middle, open to the air at both ends, 5 cm from the axis. In the spinning frame the water is at rest under a centrifugal pull, so the pressure falls from atmospheric at each meniscus to its lowest on the axis, as a parabola. 10 thousand rpm puts −1.3 MPa there, 20 thousand rpm puts −5.4 MPa there, 30 thousand rpm puts −12.2 MPa there and 45 thousand rpm puts −27.6 MPa there. The place the water is stretched hardest is the place furthest from both free surfaces, which is the whole merit of the method: a gas cannot reach the liquid where it is weakest.

A breaking strength that is the size of a flaw

Water can be stretched, and how far is a measurement people have made for a century and a half with instruments that agree with one another and not with the theory. Spinning a tube puts the stretch where no gas can reach it, sealing one caps the stretch at water's density maximum, and every measured number turns out to name the size of the worst cavity in the sample.

misconceptions · Suction

A litre of water at the crown carries 77 mL of gas it cannot hold. The volume of free gas a litre of air-saturated water can release at a siphon's crown, at the crown's own pressure, against that pressure, on a logarithmic scale, at three temperatures. It is zero at atmospheric and grows without limit towards the vapour pressure. At the reference siphon's starting crown pressure of 51.5 kPa it is 20.6 mL, a supersaturation of 2.02; at the frictionless floor of 23.0 kPa it is 76.7 mL, a supersaturation of 4.79. Cold water carries more: 87.4 mL at 5 °C. This is the equilibrium bound — what would come out if the water stayed long enough, which it does not.

The air that breaks a siphon nothing else can

A running siphon's heights cannot break it, and its friction only postpones the moment it is most exposed. What does break a siphon that has run for a day is the air dissolved in its water, which the crown's low pressure leaves the water carrying far more of than it can hold — and which gathers only once the flow is too slow to carry a bubble away.

misconceptions · Siphon

Named alongside it

The objects these essays reach for when they reach for this one.

Cavitation Surface tension Absolute pressure Liquid tension Misconception Model limit Vapour pressure Bubble Bubble dynamics Compressibility Density Induction time

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