Diffusion — where it appears
Named by 20 essays across 5 fields — each of them below, with the objects they name alongside it.
Two slow things make a fast one
Shear stretches a slug of dye and mixes nothing, because it is reversible. Molecular diffusion is hopeless at any scale bigger than a hair. Put the two together in a pipe and the dye spreads along it with an effective diffusivity two million times the molecular one — which gets larger as the molecular one gets smaller.
The other layer, and the one number that separates them
A wall in a stream carries two boundary conditions and grows two layers. Their thicknesses differ by a factor of twenty across ordinary fluids, and at exactly one Prandtl number the two profiles are not similar but identical.
How far a parcel gets
Turbulent transport is one integral. A parcel carried by a fluctuating velocity goes in a straight line while it still remembers its own motion and performs a random walk once it has forgotten, and the crossover is the correlation time — so an eddy diffusivity is not a property a flow has, it is the limit of a measurement that has run for long enough.
The bath that was only ever a wait
The Coriolis force is far too weak to steer a draining bath, and it does steer a large enough tank that has been left alone long enough. Both are true, and the number that separates them is not a force ratio — it is how many turns the earth's contribution gets through before the vessel is empty.
The scalar has its own cascade
Below the Kolmogorov scale there is no turbulence left, and a dye stirred into the flow goes on cascading anyway — on a spectrum whose exponent is minus one and whose amplitude contains no velocity spectrum at all. Resolving it costs the three-halves power of the Schmidt number, which for dye in water is a factor of ninety thousand.
The drag that integrates a whole history
A particle released in still air does not stop exponentially. The unsteady drag on it carries a term that is an integral over everything the particle has already done, weighted by the inverse square root of how long ago — so there is no time constant, and five particle time constants later it is still moving four times faster than the quasi-steady answer allows.
The wall the fluid is listening to
Water two millimetres above a moving wall is responding to what the wall did two thirds of a second ago — most likely. Half of its response is older than four and a half seconds, a tenth is older than two minutes, and the average age of what it is responding to does not exist at all.
A wake that keeps the drag and forgets the body
Two very different wakes with the same momentum deficit converge to the same profile, because the deficit is conserved and everything else diffuses away. The convergence is a power law rather than an exponential, so it takes two hundred widths for twenty per cent agreement and nine hundred for five.
How long a fluid takes to forget it was not rotating
Spin a container of water and the fluid inside reaches solid-body rotation in a hundred seconds rather than the three hours diffusion would need. The shortcut is the thin layers on the end walls, and the advantage they give is exactly the reciprocal of the square root of the Ekman number.
A duct that forgets everything but one number
Whatever is fed into a pipe, what survives a little way down it is one shape. The disturbance's higher modes decay as the square of their mode number, so the sixth is gone in thirteen centimetres where the first survives four and a half metres — and the entrance length is that one mode's decay rate and an arbitrary threshold.
The pulse that has to travel
In a rigid tube the Womersley number decides the shape of an oscillating flow. Make the wall elastic and the pressure pulse has to travel, a second number appears — the tube's length in wavelengths — and the first number turns out to decide something more basic than the profile: whether the tube carries a wave at all, or only a disturbance that spreads like heat.
The best a tube can do is its own radius
Taylor's dispersion coefficient rises without limit with velocity, so there is no best speed to run a tube at. Ask instead how much a slug spreads per metre travelled and an optimum appears at once — and the spreading there is the tube's radius over the square root of three, with no diffusivity and no velocity left in it.
When the flux outruns the pressure
A kinematic wave is derived by throwing the momentum equation away, and the derivation never says when that is allowed. It is allowed until the kinematic wave, which travels faster than the water, overtakes the downstream dynamic wave as well — at which point uniform flow ceases to exist and a concrete chute carries a train of surges instead of a sheet.
Transport with nothing transported
Taylor's mechanism needs shear and diffusion and nothing else — and in particular it does not need a mean flow. Oscillate a tube about a fixed position and the tracer still spreads along it, by hundreds of times the molecular rate, which is how a patient is ventilated with a tidal volume smaller than the airway it goes down.
The further apart, the faster they part
Release two specks of smoke close together in turbulence and the distance between them does not diffuse the way a single speck wanders. It grows faster the larger it already is, because larger separations are pulled apart by larger eddies — as the cube of the time, forgetting where it started. The law is ninety years old, its constant is still argued about, and it needs a very large flow to be seen at all.
A viscosity the flow cannot decide
Spheres stirred into a liquid thicken it by a definite amount. Rods do not. A rod in a shear flow tumbles round a closed orbit, the flow never moves it to another, and the extra viscosity depends on which orbit it is on. The equations of slow flow permit a whole range of values and choose none of them. The smallest amount of noise chooses one, and it does not matter how small.
A pair's memory shapes the cloud it spreads into
Richardson's diffusion of pair separations has no memory: each moment's push is independent of the last, and the cloud of separations grows as t³ with a peaked shape and long tails. Real pairs keep their relative velocity for about the turnover time of eddies their own size. Give them that memory and the cube law survives, because it is dimensional, but everything else about the cloud changes: its constant falls, its tails shrink, and its shape becomes a measure of how long a pair remembers. A memory of a tenth of a turnover time already takes the kurtosis from 3.76 to 2.5.
A crown dissolves its nuclei or breaks on them, and fast
A siphon of degassed water runs until its crown's tension reaches the breaking threshold of its largest nucleus. A nucleus lodged at the crown does not stay the size it arrived: it gains or loses gas by diffusion, and across a micron diffusion takes milliseconds, so the crown gives its verdict almost at once. Every stable nucleus loses gas unless the water holds more than half the crown's tension, and past a knee in gas content, dissolved air takes height from a siphon's crown that no amount of further degassing gives back.
A crevice keeps the nucleus a free bubble loses
A free bubble at a siphon's crown dissolves in milliseconds, so it cannot be what breaks a siphon that has run for an hour. A pocket of gas in a crack of the hose wall can be, because its meniscus is curved by the wall and need not dissolve. Followed through its equilibria, the pocket escapes at a tension set almost entirely by the crack's mouth. What the wall's wettability decides is slower and more consequential: whether the crack fills, or keeps drawing gas in until the siphon breaks.
What holds the shear decides whether the waves last
Holmboe's travelling waves need a density interface about half as thick as the shear around it, and diffusion thickens both. If the shear layer is held at its thickness, the interface catches up — in under a minute for heat in a laboratory tank, over an hour for salt — and the waves get two e-folds or a hundred and seventy. If the shear layer is free it thickens faster than the interface, the ratio heads to the root of the Prandtl number, and the waves last until the Richardson number ends them instead.
Named alongside it
The objects these essays reach for when they reach for this one.
Model limitMeasurementTransportDispersionMemory kernelModel validityPeclet numberRegimeDimensionlessMixingRelaxation timeBoundary condition