Concept

Peclet number — where it appears

The ratio of advective transport to diffusive transport for a scalar carried by a flow. It decides the thickness of a thermal or concentration layer relative to the velocity layer, and at large values the two are separated by a factor that is a power of it.

Named by 13 essays across 3 fields — each of them below, with the objects they name alongside it.

A million times faster, and the constant is 48.0. The effective diffusivity along a pipe, divided by the molecular one, against the Péclet number — both logarithmic. Below Pe ≈ 7 the tracer simply diffuses and the curve is flat at one. Above it the dispersion is all Taylor's, rising as the square of the Péclet number, so a thousandfold Péclet number is a millionfold enhancement. The constant in D(1 + Pe²/48) is not quoted here: it is recovered from a numerical solution of the cell problem across the section, giving 48.0000 for a tube and 52.5 for a plane channel, which is Aris' 2/105.

Two slow things make a fast one

Shear stretches a slug of dye and mixes nothing, because it is reversible. Molecular diffusion is hopeless at any scale bigger than a hair. Put the two together in a pipe and the dye spreads along it with an effective diffusivity two million times the molecular one — which gets larger as the molecular one gets smaller.

regimes · Dispersion
One layer, and the four others inside and outside it. The velocity profile over a flat plate, and the temperature profile in the same layer at four Prandtl numbers: a liquid metal at 0.01, air at 0.71, water at 7 and a heavy oil at 100. The equations differ by one number and the profiles differ by a factor of twenty in thickness. At Pr = 1 the two are the same function — not similar, identical, to eight decimal places — because the equations and the conditions are then the same, which is what every statement called a Reynolds analogy rests on.

The other layer, and the one number that separates them

A wall in a stream carries two boundary conditions and grows two layers. Their thicknesses differ by a factor of twenty across ordinary fluids, and at exactly one Prandtl number the two profiles are not similar but identical.

regimes · Peclet
Ballistic first, diffusive later. The mean square displacement of a parcel carried by a fluctuating velocity, from Taylor's 1921 integral with an exponential correlation of time scale 1. Below the correlation time it follows the straight-line law u²t² exactly — the parcel has not yet changed its mind — and above it the curve joins the diffusion law 2u²T·t, offset by the head start the ballistic phase gave it. The eddy diffusivity is u²T = 1.000, and it is a property of the correlation rather than of any equation of motion.

How far a parcel gets

Turbulent transport is one integral. A parcel carried by a fluctuating velocity goes in a straight line while it still remembers its own motion and performs a random walk once it has forgotten, and the crossover is the correlation time — so an eddy diffusivity is not a property a flow has, it is the limit of a measurement that has run for long enough.

turbulence · Mixing
The number a duct settles at is an eigenvalue. The local Nusselt number against x⁺ = x/(D·Re·Pr), from a Crank–Nicolson march that contains no eigenvalue anywhere. It settles at 3.6568, which is λ₀²/2 for the Graetz eigenvalue problem — a completely separate calculation. The mark at x⁺ = 0.05 is the entry length every textbook quotes: it delivers a Nusselt number 1.45 per cent above the developed value, which is a perfectly reasonable tolerance and is never the one stated.

How far before the heat arrives

A duct's thermal entry length is quoted everywhere as x/(D·Re·Pr) = 0.05, with no tolerance attached. Working out what it delivers gives a Nusselt number 1.45 per cent above the developed value — and the developed value itself is not a term ratio at all but an eigenvalue, 3.6568, which is also the rate at which the duct forgets its inlet.

regimes · Peclet
When the tracer leaves, given when it went in. The residence-time distribution of three beds with the same mean residence time and different Peclet numbers. Every one of them has its mean at exactly one, and they are nothing alike: the loosest lets a tenth of the tracer out before a third of the mean time has passed, and the tightest is nearly the spike a plug-flow calculation assumes.

The outlet is the inlet, a while ago

A bed has a mean residence time and everybody quotes it. Six beds with the same mean let their first hundredth through at 0.20 and at 0.85 of it, mix a window of inlet history between 1.53 and 0.18 wide, and convert a first-order reaction by amounts the mean cannot distinguish.

applied · Porous
The scalar spectrum, with its two ranges. A model scalar spectrum at a Schmidt number of two thousand — dye in water. Below the Kolmogorov wavenumber it is Obukhov and Corrsin's five-thirds, inherited from the velocity; above it there is no turbulence left and the spectrum is Batchelor's minus one, which contains no velocity spectrum at all.

The scalar has its own cascade

Below the Kolmogorov scale there is no turbulence left, and a dye stirred into the flow goes on cascading anyway — on a spectrum whose exponent is minus one and whose amplitude contains no velocity spectrum at all. Resolving it costs the three-halves power of the Schmidt number, which for dye in water is a factor of ninety thousand.

turbulence · Mixing
Where the eddies outconduct the molecules. The ratio of turbulent to molecular heat diffusivity across the pipe at Reτ = 2000, for five fluids, on logarithmic axes. Wherever it is above one the eddies carry more heat than conduction does. For air it passes one inside the buffer layer and reaches 135; for water, earlier and higher. For liquid sodium it never reaches one anywhere: at its peak, halfway to the axis, the eddies carry just over half what conduction carries, and the temperature profile is set by conduction across the whole pipe.

The heat the eddies do not carry

In a laminar layer the temperature and the velocity have different thicknesses in every fluid but one. In a turbulent pipe the eddies carry both, and the difference nearly vanishes — for air, water and oil alike. It does not vanish for a liquid metal, whose molecules conduct heat faster than the eddies can, and the boundary between the two behaviours is a Péclet number of about four hundred at every Reynolds number.

regimes · Peclet
The spreading per metre has a best speed; the spreading per second has none. The plate height — how much variance a slug picks up per unit length travelled — against the velocity, for four retention factors. Each curve falls as one over the velocity, because molecular diffusion along the tube matters when the flow is slow, and rises with it, because that is Taylor's dispersion. The minimum is what a chromatograph is run at, and Taylor's effective diffusivity has no such point anywhere.

The best a tube can do is its own radius

Taylor's dispersion coefficient rises without limit with velocity, so there is no best speed to run a tube at. Ask instead how much a slug spreads per metre travelled and an optimum appears at once — and the spreading there is the tube's radius over the square root of three, with no diffusivity and no velocity left in it.

regimes · Dispersion
What an oscillation carries, against how fast it is asked. The extra axial diffusivity of a zero-mean oscillation, at fixed velocity amplitude, against the Womersley number. At low frequency it is exactly Taylor's dispersion evaluated at the mean square velocity — the profile has time to be Poiseuille's at every instant. At high frequency the shear is confined to a Stokes layer, the tracer in the core is never sheared, and the transport falls as the cube of the Womersley number.

Transport with nothing transported

Taylor's mechanism needs shear and diffusion and nothing else — and in particular it does not need a mean flow. Oscillate a tube about a fixed position and the tracer still spreads along it, by hundreds of times the molecular rate, which is how a patient is ventilated with a tidal volume smaller than the airway it goes down.

regimes · Dispersion
A washed filter's best cycle is shorter, and still has one. The filtrate a batch filter produces per hour, averaged over filtering, washing and twenty minutes of emptying and refilling, against the filtrate collected in each cycle, for a slurry of 400 kilograms of silica per cubic metre and wash ratios of 0, 1, 2 and 5 pore volumes. Each curve has a best cycle, marked, and the wash both lowers it and moves it to a thinner cake: from 0.307 to 0.217 m³ per m² of cloth.

A washed filter works as long as it rests

A batch filter that has to be emptied between runs has a best cycle, and the rule for it is exact: the time the cake is responsible for equals the time the filter stands idle. Washing the cake does not break the rule, because a wash through a finished cake costs time in proportion to the square of its thickness, just as filtering it did. What a wash changes is the price, and the price is set by the slurry's concentration and by how far the wash front smears, not by the cake's softness.

applied · Porous
The entrance grows with the Péclet number, peaks, and then shrinks. The distance from a wall-temperature step at which the local Nusselt number has come within 5 per cent of its developed value, in diameters, against the Péclet number, for turbulent pipes at Reτ = 500, 1000, 2000 and 5000, with the slug's laminar line L/D = 0.029·Pe. The liquid metals sit on the line; the entrance peaks at 11.6 diameters at Pe ≈ 4700 for Reτ = 1000 and falls to about three and a half diameters for water.

The longest thermal entrance belongs to neither metal nor gas

A liquid metal carries its heat across a turbulent pipe by conduction, as a laminar flow would, and so its thermal entrance should be long. It is long only when its Péclet number is large. Below a few hundred the entrance grows in proportion to the Péclet number with the constant of a fluid moving as a solid block, and it leaves that scaling close to the threshold at which the eddies first match conduction. The longest entrance in a turbulent pipe belongs to the fluids between the metals and the gases, and how long it is depends on a number the measurements have never pinned down.

regimes · Peclet
A resistive wall lengthens a slug's thermal entrance by half, and no more. The 5 per cent thermal entrance length of a slug flow, as a multiple of its length with the wall held at a fixed temperature, against the wall Biot number hw·D/kf. A wall that conducts well changes nothing; as the wall's resistance grows the entrance lengthens to a peak of 1.501 times at a Biot number of 2.29, and then shortens slightly to 1.457 times, the fixed-flux value, for a wall that conducts hardly at all.

A steel wall lengthens a sodium entrance by half

A liquid metal's thermal entrance is long because its heat crosses the pipe by conduction, and a steel tube conducts a tenth as well as sodium, so the wall is part of the path. Put it in series with the fluid and the entrance does grow — but by half at the very most, at a wall Biot number near two, which is where sodium in a steel tube happens to sit. A wall that resists more changes the boundary condition from a fixed temperature to a fixed flux, not the length.

regimes · Peclet
A travelling bubble's B-factor grows as the square root of its age, and the bubble turns heat-limited when it reaches B*. The vapour a growing bubble has made over the liquid it has cooled, against its age, in water at 80 °C under a tension 10 kPa below the vapour pressure, while inertia limits its growth; the dashed line is B, at which the cooling would use up the whole tension. B is 4.3 at a microsecond and 136 at a millisecond, and meets B = 31.6 at 53.8 µs, when its radius is 0.141 mm.

A bubble is throttled by its age, and a sheet by its length

A cavity cools the liquid it boils, and the cooling lowers the vapour pressure it needed. Whether that matters was a question about one number, the B-factor — vapour made over liquid cooled — and no real cavity's was known. Computed, the two kinds a pump has are nothing alike. A travelling bubble cools a thin shell that thins further as it stretches, so its B grows as the square root of its age and reaches the critical value at Brennen's thermal time: a millisecond in water at 60 °C, four microseconds at the boiling point. An attached sheet keeps renewing the liquid it cools, so its B is a few, fixed by its length and speed. In warm water the bubbles are suppressed forty degrees before the sheet.

applied · Cavitation

Named alongside it

The objects these essays reach for when they reach for this one.

Model limitDiffusionDispersionDimensionlessMeasurementTransportHeat transferPrandtl numberResidence timeEigenvalueMixingNusselt number

All concepts