Concept

Peclet number — where it appears

The ratio of advective transport to diffusive transport for a scalar carried by a flow. It decides the thickness of a thermal or concentration layer relative to the velocity layer, and at large values the two are separated by a factor that is a power of it.

Named by 7 essays across 3 fields — each of them below, with the objects they name alongside it.

A million times faster, and the constant is 48.0. The effective diffusivity along a pipe, divided by the molecular one, against the Péclet number — both logarithmic. Below Pe ≈ 7 the tracer simply diffuses and the curve is flat at one. Above it the dispersion is all Taylor's, rising as the square of the Péclet number, so a thousandfold Péclet number is a millionfold enhancement. The constant in D(1 + Pe²/48) is not quoted here: it is recovered from a numerical solution of the cell problem across the section, giving 48.0000 for a tube and 52.5 for a plane channel, which is Aris' 2/105.

Two slow things make a fast one

Shear stretches a slug of dye and mixes nothing, because it is reversible. Molecular diffusion is hopeless at any scale bigger than a hair. Put the two together in a pipe and the dye spreads along it with an effective diffusivity two million times the molecular one — which gets larger as the molecular one gets smaller.

regimes · Dispersion
One layer, and the four others inside and outside it. The velocity profile over a flat plate, and the temperature profile in the same layer at four Prandtl numbers: a liquid metal at 0.01, air at 0.71, water at 7 and a heavy oil at 100. The equations differ by one number and the profiles differ by a factor of twenty in thickness. At Pr = 1 the two are the same function — not similar, identical, to eight decimal places — because the equations and the conditions are then the same, which is what every statement called a Reynolds analogy rests on.

The other layer, and the one number that separates them

A wall in a stream carries two boundary conditions and grows two layers. Their thicknesses differ by a factor of twenty across ordinary fluids, and at exactly one Prandtl number the two profiles are not similar but identical.

regimes · Peclet
Ballistic first, diffusive later. The mean square displacement of a parcel carried by a fluctuating velocity, from Taylor's 1921 integral with an exponential correlation of time scale 1. Below the correlation time it follows the straight-line law u²t² exactly — the parcel has not yet changed its mind — and above it the curve joins the diffusion law 2u²T·t, offset by the head start the ballistic phase gave it. The eddy diffusivity is u²T = 1.000, and it is a property of the correlation rather than of any equation of motion.

How far a parcel gets

Turbulent transport is one integral. A parcel carried by a fluctuating velocity goes in a straight line while it still remembers its own motion and performs a random walk once it has forgotten, and the crossover is the correlation time — so an eddy diffusivity is not a property a flow has, it is the limit of a measurement that has run for long enough.

turbulence · Mixing
The number a duct settles at is an eigenvalue. The local Nusselt number against x⁺ = x/(D·Re·Pr), from a Crank–Nicolson march that contains no eigenvalue anywhere. It settles at 3.6568, which is λ₀²/2 for the Graetz eigenvalue problem — a completely separate calculation. The mark at x⁺ = 0.05 is the entry length every textbook quotes: it delivers a Nusselt number 1.45 per cent above the developed value, which is a perfectly reasonable tolerance and is never the one stated.

How far before the heat arrives

A duct's thermal entry length is quoted everywhere as x/(D·Re·Pr) = 0.05, with no tolerance attached. Working out what it delivers gives a Nusselt number 1.45 per cent above the developed value — and the developed value itself is not a term ratio at all but an eigenvalue, 3.6568, which is also the rate at which the duct forgets its inlet.

regimes · Peclet
When the tracer leaves, given when it went in. The residence-time distribution of three beds with the same mean residence time and different Peclet numbers. Every one of them has its mean at exactly one, and they are nothing alike: the loosest lets a tenth of the tracer out before a third of the mean time has passed, and the tightest is nearly the spike a plug-flow calculation assumes.

The outlet is the inlet, a while ago

A bed has a mean residence time and everybody quotes it. Six beds with the same mean let their first hundredth through at 0.20 and at 0.85 of it, mix a window of inlet history between 1.53 and 0.18 wide, and convert a first-order reaction by amounts the mean cannot distinguish.

applied · Porous
The scalar spectrum, with its two ranges. A model scalar spectrum at a Schmidt number of two thousand — dye in water. Below the Kolmogorov wavenumber it is Obukhov and Corrsin's five-thirds, inherited from the velocity; above it there is no turbulence left and the spectrum is Batchelor's minus one, which contains no velocity spectrum at all.

The scalar has its own cascade

Below the Kolmogorov scale there is no turbulence left, and a dye stirred into the flow goes on cascading anyway — on a spectrum whose exponent is minus one and whose amplitude contains no velocity spectrum at all. Resolving it costs the three-halves power of the Schmidt number, which for dye in water is a factor of ninety thousand.

turbulence · Mixing
Where the eddies outconduct the molecules. The ratio of turbulent to molecular heat diffusivity across the pipe at Reτ = 2000, for five fluids, on logarithmic axes. Wherever it is above one the eddies carry more heat than conduction does. For air it passes one inside the buffer layer and reaches 135; for water, earlier and higher. For liquid sodium it never reaches one anywhere: at its peak, halfway to the axis, the eddies carry just over half what conduction carries, and the temperature profile is set by conduction across the whole pipe.

The heat the eddies do not carry

In a laminar layer the temperature and the velocity have different thicknesses in every fluid but one. In a turbulent pipe the eddies carry both, and the difference nearly vanishes — for air, water and oil alike. It does not vanish for a liquid metal, whose molecules conduct heat faster than the eddies can, and the boundary between the two behaviours is a Péclet number of about four hundred at every Reynolds number.

regimes · Peclet

Named alongside it

The objects these essays reach for when they reach for this one.

DiffusionDimensionlessDispersionHeat transferMeasurementMixingTransportTurbulenceCorrelationModel limitPrandtl numberResidence time

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