Concept

Dispersion — where it appears

The spreading of a marked quantity through a flow, and separately the dependence of a wave's speed on its wavelength. Both senses appear in this collection, and each is a case where a rate is decided by a combination of two mechanisms rather than one.

Named by 19 essays across 7 fields — each of them below, with the objects they name alongside it.

The Kelvin wake, and the angle it comes out at. The wake behind something moving over deep water. Each curve joins everything radiated at one moment, wherever it has since travelled to. All of it stays inside a wedge whose half-angle is the inverse sine of one third, about nineteen and a half degrees, and that number does not depend on the speed, on gravity, or on the size of the vessel.

The angle that does not care

Every ship on deep water leaves a wake inside a wedge of the same angle. Not roughly the same — the same, for a rowing boat and a supertanker, at any speed either of them can manage, on any planet with any gravity.

regimes · Froude
A million times faster, and the constant is 48.0. The effective diffusivity along a pipe, divided by the molecular one, against the Péclet number — both logarithmic. Below Pe ≈ 7 the tracer simply diffuses and the curve is flat at one. Above it the dispersion is all Taylor's, rising as the square of the Péclet number, so a thousandfold Péclet number is a millionfold enhancement. The constant in D(1 + Pe²/48) is not quoted here: it is recovered from a numerical solution of the cell problem across the section, giving 48.0000 for a tube and 52.5 for a plane channel, which is Aris' 2/105.

Two slow things make a fast one

Shear stretches a slug of dye and mixes nothing, because it is reversible. Molecular diffusion is hopeless at any scale bigger than a hair. Put the two together in a pipe and the dye spreads along it with an effective diffusivity two million times the molecular one — which gets larger as the molecular one gets smaller.

regimes · Dispersion
Four turns of a wave, and the parcel is not back. Two parcels traced through four periods of a linear deep-water wave of steepness 0.1, by integrating the exact velocity field. Each orbit is very nearly a closed circle and misses closing by a little, every time, in the same direction — that miss is the whole of the Stokes drift. The near-surface parcel advances 0.0357 of a wavelength over the four cycles and the one a tenth of a wavelength down advances 0.0122, a third as far — because the drift falls off twice as fast with depth as the orbit's own size does.

The drift in a wave that has none

The velocity at any fixed point under a passing wave averages to exactly zero, and every parcel of water in it moves steadily forward anyway. The orbits do not close, they miss by the same amount every time, and the missing amount is the square of the steepness times the wave speed.

kinematics · Stokes drift
Ballistic first, diffusive later. The mean square displacement of a parcel carried by a fluctuating velocity, from Taylor's 1921 integral with an exponential correlation of time scale 1. Below the correlation time it follows the straight-line law u²t² exactly — the parcel has not yet changed its mind — and above it the curve joins the diffusion law 2u²T·t, offset by the head start the ballistic phase gave it. The eddy diffusivity is u²T = 1.000, and it is a property of the correlation rather than of any equation of motion.

How far a parcel gets

Turbulent transport is one integral. A parcel carried by a fluctuating velocity goes in a straight line while it still remembers its own motion and performs a random walk once it has forgotten, and the crossover is the correlation time — so an eddy diffusivity is not a property a flow has, it is the limit of a measurement that has run for long enough.

turbulence · Mixing
The sound speed of a mixture, against how much of it is gas. Wood's formula for air in water. Both ends are the pure phases at 343 and 1,481 metres a second; in between the mixture takes the water's inertia and the air's springiness and the speed collapses to twenty-four metres a second — a fourteenth of the slower constituent.

Slower than either of them

Sound travels at 343 metres a second in air and 1,481 in water. In a mixture of the two it travels at twenty-four, because the mixture takes the water's inertia and the air's springiness — and one per cent of air by volume is enough to take water down to a twelfth of its own speed.

compressible · Speed of sound
Six orbits that do not close. One parcel's path under a linear deep-water wave of steepness 0.05, at a fifth of a wavelength down, released at the phase that centres the orbit on its release depth. Each loop returns almost to where it began and not quite.

A drift made of two things that average to zero

Stokes drift is usually explained as a parcel spending longer in the forward half of its orbit. That is true and it is not a formula. The formula is a correlation between a displacement and a gradient, each of which averages to exactly nothing, and it splits into two halves that are equal to twelve figures.

kinematics · Stokes drift
When the tracer leaves, given when it went in. The residence-time distribution of three beds with the same mean residence time and different Peclet numbers. Every one of them has its mean at exactly one, and they are nothing alike: the loosest lets a tenth of the tracer out before a third of the mean time has passed, and the tightest is nearly the spike a plug-flow calculation assumes.

The outlet is the inlet, a while ago

A bed has a mean residence time and everybody quotes it. Six beds with the same mean let their first hundredth through at 0.20 and at 0.85 of it, mix a window of inlet history between 1.53 and 0.18 wide, and convert a first-order reaction by amounts the mean cannot distinguish.

applied · Porous
Three exponents for one dimensionless group. The local slope of each error, measured over one decade at a time. The duct's is exactly 1, the long wave's is exactly 2, and the slender body's drifts from 1.900 to 1.733 across the range and never reaches either. The same geometric ratio, in three problems that look alike, and the third one has no exponent at all.

One group, three exponents

Lubrication theory, shallow water and slender-body theory are taught in three places and are one expansion in one group — a ratio of two lengths, with no speed, no viscosity and no fluid in it at all. The error is supposed to be second order. In three problems that look alike it is first order, second order, and an exponent that does not exist.

regimes · Slenderness
The free surface a submerged body leaves behind it, and the flat water in front. The linearised free-surface problem solved as a Fourier integral with a radiation condition. Behind the body a wave train of the wavelength that stands still relative to it, 2 pi U²/g; ahead of it, an amplitude a hundred and twenty times smaller. The asymmetry is the drag: an ideal fluid with a free surface can carry energy away.

The drag that is made of waves

D'Alembert's paradox says a body in a steady, irrotational, incompressible, inviscid flow feels no drag. Put a free surface above it and every one of those words still holds — and the drag is not zero. It is the energy walking away in the wave train behind.

inviscid · Dalembert
A wave that travels and a wave that spreads. A harmonic pressure wave's amplitude and its instantaneous value along a tube, over two wavelengths of the inviscid wave, at four Womersley numbers. At α = 15 the wave marches on, a little weaker each wavelength. At α = 5 it is visibly damped. At α = 2 it is nearly gone within a wavelength. At α = 0.5 there is no wave to speak of: the disturbance falls away within a small fraction of the inviscid wavelength, as heat does into a wall.

The pulse that has to travel

In a rigid tube the Womersley number decides the shape of an oscillating flow. Make the wall elastic and the pressure pulse has to travel, a second number appears — the tube's length in wavelengths — and the first number turns out to decide something more basic than the profile: whether the tube carries a wave at all, or only a disturbance that spreads like heat.

regimes · Womersley
The spreading per metre has a best speed; the spreading per second has none. The plate height — how much variance a slug picks up per unit length travelled — against the velocity, for four retention factors. Each curve falls as one over the velocity, because molecular diffusion along the tube matters when the flow is slow, and rises with it, because that is Taylor's dispersion. The minimum is what a chromatograph is run at, and Taylor's effective diffusivity has no such point anywhere.

The best a tube can do is its own radius

Taylor's dispersion coefficient rises without limit with velocity, so there is no best speed to run a tube at. Ask instead how much a slug spreads per metre travelled and an optimum appears at once — and the spreading there is the tube's radius over the square root of three, with no diffusivity and no velocity left in it.

regimes · Dispersion
What an oscillation carries, against how fast it is asked. The extra axial diffusivity of a zero-mean oscillation, at fixed velocity amplitude, against the Womersley number. At low frequency it is exactly Taylor's dispersion evaluated at the mean square velocity — the profile has time to be Poiseuille's at every instant. At high frequency the shear is confined to a Stokes layer, the tracer in the core is never sheared, and the transport falls as the cube of the Womersley number.

Transport with nothing transported

Taylor's mechanism needs shear and diffusion and nothing else — and in particular it does not need a mean flow. Oscillate a tube about a fixed position and the tracer still spreads along it, by hundreds of times the molecular rate, which is how a patient is ventilated with a tidal volume smaller than the airway it goes down.

regimes · Dispersion
Three pairs released at different distances end on one line. The mean square separation of two parcels against time, both in Kolmogorov units, for pairs released one, thirty and a thousand Kolmogorov lengths apart in turbulence whose integral scale is a million of them. Each starts flat — the pair has not yet moved — and each joins the same line, g ε t³ with g = 0.5, after which nothing about where it started survives. Beyond the integral scale all three become ordinary diffusion, growing as t.

The further apart, the faster they part

Release two specks of smoke close together in turbulence and the distance between them does not diffuse the way a single speck wanders. It grows faster the larger it already is, because larger separations are pulled apart by larger eddies — as the cube of the time, forgetting where it started. The law is ninety years old, its constant is still argued about, and it needs a very large flow to be seen at all.

turbulence · Mixing
Hull speed is not the hump. The wave-resistance coefficient of the Wigley hull, R/(½ρU²S) in thousandths, against the Froude number U/√(gL), from Michell's thin-ship integral. The curve rises through a series of humps and hollows and peaks at Fr = 0.499. The hull-speed rule's Froude number, 1/√(2π) = 0.399, where the transverse wave is as long as the hull, is neither: it lies on the steep climb between the last hollow, at 0.346, and the main hump.

Hull speed is not the hump

The hull-speed rule says a displacement vessel meets a wall where its wave is as long as its hull, at a Froude number of 0.4. Michell's thin-ship integral, computed for a standard hull, puts that speed on the steep climb between the last hollow and the main hump, and the hump itself at 0.5. Past the hump the wave resistance grows more slowly than the speed. The hollows sit where the hull's own transverse wave switches off, and a bulb that cancels at one speed multiplies the resistance at another.

regimes · Froude
A washed filter's best cycle is shorter, and still has one. The filtrate a batch filter produces per hour, averaged over filtering, washing and twenty minutes of emptying and refilling, against the filtrate collected in each cycle, for a slurry of 400 kilograms of silica per cubic metre and wash ratios of 0, 1, 2 and 5 pore volumes. Each curve has a best cycle, marked, and the wash both lowers it and moves it to a thinner cake: from 0.307 to 0.217 m³ per m² of cloth.

A washed filter works as long as it rests

A batch filter that has to be emptied between runs has a best cycle, and the rule for it is exact: the time the cake is responsible for equals the time the filter stands idle. Washing the cake does not break the rule, because a wash through a finished cake costs time in proportion to the square of its thickness, just as filtering it did. What a wash changes is the price, and the price is set by the slurry's concentration and by how far the wash front smears, not by the cake's softness.

applied · Porous
Dry air makes a slow bang. The 10-to-90 per cent rise time of a steady shock against relative humidity, for jumps of 25, 50 and 90 pascals, all below the strength at which a discontinuity returns. Each falls roughly as the nitrogen relaxation time does, and doubles when the jump is halved. The rule marks the thermoviscous rise time of the 50-pascal shock, a few microseconds — two to three orders of magnitude below any of the curves.

Oxygen makes a boom's crack, nitrogen its rise time

The shock at the front of a sonic boom is not the viscous shock of a textbook, a few microseconds thick. It is spread over a large fraction of a millisecond by the vibrational relaxation of the air's molecules, and the two gases do different jobs. Oxygen, fast, removes the discontinuity for any boom weaker than about ninety pascals and decides how much of the front is left at the frequencies the ear weighs most; nitrogen, slow, sets the rise time that is measured. Water vapour speeds both, so a dry day makes a softer bang.

compressible · Sonic boom
On Mars the bulk viscosity is two speeds of sound. The speed of sound in carbon dioxide at 610 pascals and 240 kelvin against frequency, with the bulk viscosity scaled from its value at one atmosphere by pressure alone. Low notes travel at 245 m/s, with the bending vibration keeping up; high ones at 252 m/s, with it frozen. The step is centred near 342 Hz. The Perseverance rover's microphones reported the same thing in 2022: two speeds of sound, near 240 and 250 metres a second, either side of a few hundred hertz.

The largest bulk viscosity is the first to expire

A bulk viscosity is not a separate property of a gas. It is the time a molecule's internal motion takes to catch up with a compression, multiplied by the pressure and by how much heat capacity lags, and read from below that time's frequency. So the coefficient that is largest is the one that stops being a coefficient soonest: carbon dioxide's fifteen-hundred-fold value is ten per cent wrong at 24 kHz, and on Mars it is two speeds of sound in the audible band.

viscous · Bulk viscosity
Below the bubbles' resonance the mixture is slow; above its stop band it is faster than water. The phase speed of sound in water carrying millimetre air bubbles, against frequency, at void fractions of 10⁻⁴, 10⁻³ and 10⁻². At low frequency each is Wood's mixture speed with the gas isothermal — 312 m/s at 10⁻³, not the 366 an adiabatic gas would give. Approaching the bubbles' resonance near 3.2 kHz the speed falls further, then jumps through a stop band in which the wave hardly propagates, and above it the phase speed exceeds water's — at 10⁻³ 1640 m/s at 30 kHz — before returning to 1481 m/s from above.

Above their resonance, bubbles make water faster

Wood's formula says a pinch of air makes water's sound slower than air's, and it is right at low frequency. Each bubble, though, is a spring with water for its mass, and the wave drives it. Below the bubbles' resonance the mixture is slow; through a band above it no sound propagates at all; and above that band the same bubbly water carries sound faster than pure water does. Even the slow end is not quite Wood's, because a slowly squeezed bubble keeps its heat.

compressible · Speed of sound
A sphere two per cent larger overtakes its neighbour round a path that is its own mirror image, and leaves at the offset it came in at. The centre of a sphere two per cent larger than its neighbour, relative to the smaller sphere, as it overtakes it in a viscous liquid, from four horizontal offsets; the circle is the distance at which they would touch. Each path bulges outward as it passes and is symmetric about the smaller sphere's level: from 0.85, 1.5, 2.5, 4 radii the larger sphere leaves at 0.8499, 1.5, 2.5, 4, after closest approaches of 2.27, 2.83, 3.74, 5.15 radii.

A larger sphere overtakes its neighbour and leaves on the line it came in on

Two equal spheres settling together never change their shape. Make one of them two per cent larger and the pair becomes an encounter: the larger sphere sinks past the smaller round a path that bulges out and comes back, slowed sixteenfold at contact but never stopped, and it leaves at exactly the offset it arrived with. The smaller sphere swings seven radii sideways while the larger is above it and gives every radius back while the larger is below. In Stokes flow, meeting a neighbour displaces nothing — unless the spheres touch, and a hundredth of a radius of roughness is enough to make every touching path leave on the same line.

viscous · Reciprocity

Named alongside it

The objects these essays reach for when they reach for this one.

Model limitMeasurementDiffusionPeclet numberTransportCompressibilityMixingRegimeResidence timeAveragingDimensionlessFroude number

All concepts