Concept

Residence time — where it appears

How long a parcel of fluid spends inside a device between entering and leaving. Its mean is volume over flow rate and is the number usually quoted; the distribution about that mean decides when a bed first breaks through and how much a reaction converts.

Named by 6 essays across 4 fields — each of them below, with the objects they name alongside it.

A million times faster, and the constant is 48.0. The effective diffusivity along a pipe, divided by the molecular one, against the Péclet number — both logarithmic. Below Pe ≈ 7 the tracer simply diffuses and the curve is flat at one. Above it the dispersion is all Taylor's, rising as the square of the Péclet number, so a thousandfold Péclet number is a millionfold enhancement. The constant in D(1 + Pe²/48) is not quoted here: it is recovered from a numerical solution of the cell problem across the section, giving 48.0000 for a tube and 52.5 for a plane channel, which is Aris' 2/105.

Two slow things make a fast one

Shear stretches a slug of dye and mixes nothing, because it is reversible. Molecular diffusion is hopeless at any scale bigger than a hair. Put the two together in a pipe and the dye spreads along it with an effective diffusivity two million times the molecular one — which gets larger as the molecular one gets smaller.

regimes · Dispersion

The number that settles the argument. How many turns the earth's contribution gets through in the time the vessel takes to drain: the draining time divided by the rotation period at the drain. A bathtub manages a tenth of one and there is nothing to see. The apparatus that settled it manages nearly nineteen hundred, and that is the whole of what its enormous area-to-drain ratio was for.

The bath that was only ever a wait

The Coriolis force is far too weak to steer a draining bath, and it does steer a large enough tank that has been left alone long enough. Both are true, and the number that separates them is not a force ratio — it is how many turns the earth's contribution gets through before the vessel is empty.

misconceptions · Coriolis scale

When the tracer leaves, given when it went in. The residence-time distribution of three beds with the same mean residence time and different Peclet numbers. Every one of them has its mean at exactly one, and they are nothing alike: the loosest lets a tenth of the tracer out before a third of the mean time has passed, and the tightest is nearly the spike a plug-flow calculation assumes.

The outlet is the inlet, a while ago

A bed has a mean residence time and everybody quotes it. Six beds with the same mean let their first hundredth through at 0.20 and at 0.85 of it, mix a window of inlet history between 1.53 and 0.18 wide, and convert a first-order reaction by amounts the mean cannot distinguish.

applied · Porous

A duct that does not change, and a parcel that does. A contraction of area ratio four, with the parcel marked at five equal intervals of time. The walls do not move, the field at every point is the same at every instant, and the spacing of the markers grows because the parcel is carrying its own history through the duct.

How long the fluid has been in there

Age is the simplest thing a flow can remember. It obeys the shortest transport equation in the subject — its material derivative is one — and no instrument pointed at a steady flow can read it, because a steady flow's every field is constant and its fluid is getting older all the time.

kinematics · Acceleration

The spreading per metre has a best speed; the spreading per second has none. The plate height — how much variance a slug picks up per unit length travelled — against the velocity, for four retention factors. Each curve falls as one over the velocity, because molecular diffusion along the tube matters when the flow is slow, and rises with it, because that is Taylor's dispersion. The minimum is what a chromatograph is run at, and Taylor's effective diffusivity has no such point anywhere.

The best a tube can do is its own radius

Taylor's dispersion coefficient rises without limit with velocity, so there is no best speed to run a tube at. Ask instead how much a slug spreads per metre travelled and an optimum appears at once — and the spreading there is the tube's radius over the square root of three, with no diffusivity and no velocity left in it.

regimes · Dispersion

A washed filter's best cycle is shorter, and still has one. The filtrate a batch filter produces per hour, averaged over filtering, washing and twenty minutes of emptying and refilling, against the filtrate collected in each cycle, for a slurry of 400 kilograms of silica per cubic metre and wash ratios of 0, 1, 2 and 5 pore volumes. Each curve has a best cycle, marked, and the wash both lowers it and moves it to a thinner cake: from 0.307 to 0.217 m³ per m² of cloth.

A washed filter works as long as it rests

A batch filter that has to be emptied between runs has a best cycle, and the rule for it is exact: the time the cake is responsible for equals the time the filter stands idle. Washing the cake does not break the rule, because a wash through a finished cake costs time in proportion to the square of its thickness, just as filtering it did. What a wash changes is the price, and the price is set by the slurry's concentration and by how far the wash front smears, not by the cake's softness.

applied · Porous

Named alongside it

The objects these essays reach for when they reach for this one.

Measurement Dispersion Peclet number Diffusion Memory kernel Model limit Transport Dimensionless Mixing Model validity Optimisation Regime

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