Fluid Flow & Aerodynamics
why things fly, and why the usual explanation is wrong
Concept

Surfactant — where it appears

A substance that gathers at an interface and lowers its surface tension, even at very small concentrations. Gradients of its concentration make Marangoni stresses that can hold a bubble's or drop's surface still against the flow.

Named by 3 essays across one field — each of them below, with the objects they name alongside it.

Two-thirds to one, and nothing outside it. The drag on a spherical drop as a fraction of Stokes' drag on a rigid sphere of the same size, against the ratio of the viscosities. It runs from exactly two-thirds for a clean gas bubble to exactly one for a rigid particle and takes no value outside that range, however light or heavy the drop is — the formula has no density in it anywhere. A drop of water in air and a drop of mercury in water sit at opposite ends of it.

The surface that moves with the flow

A clean gas bubble feels two-thirds of the drag a rigid sphere of the same size would, and the formula has no density in it anywhere. What buys the third is that the bubble's surface is free to move — and real bubbles in ordinary water do not get it, for a reason that is a millionth of a per cent of the water by mass.

viscous · Mobile interface The drag follows the surfactant load, and a surface pressure of μU pays nearly all of it. How far the drag has climbed from the clean bubble's to the rigid sphere's, against the mean surfactant load over the whole bubble as a surface pressure in units of μU. A load of 0.2 μU makes a 60° cap and a third of the climb; 0.56 a 90° cap and 70 per cent of it; 1 a 120° cap and 94 per cent. The dashed line is the cap's share of the surface for the same caps: the drag runs ahead of the area covered.

A thousandth of a monolayer holds a bubble still

A clean bubble rising slowly through water feels two-thirds of a rigid sphere's drag, and real bubbles almost never do, because surfactant swept to the rear holds the surface still over a cap there. Solving the flow with the cap in it shows how little that takes. The drag runs ahead of the area covered — half-way to rigid with a third of the surface held — and the surfactant needed is set by the viscous stress, not by the surface tension. For a bubble a tenth of a millimetre across, a thousandth of a monolayer, spread as a cap, makes it rise within a few per cent of a solid ball.

viscous · Mobile interface The same cap costs a rising bubble a quarter of its speed and a migrating one four-fifths. Speed as a fraction of the clean bubble's against the half-angle of a stagnant cap over the rear: for a bubble migrating in a temperature gradient, and for the same bubble rising under its weight. A 90° cap leaves the rising bubble 74 per cent of its speed and the migrating one 21 per cent; a 120° cap, 68 and 4. The rising bubble can only fall to a rigid sphere's two-thirds; the migrating one falls to nothing.

A cap that slows a rising bubble stops a migrating one

Surfactant swept to the back of a bubble holds the surface still there, and for a bubble rising under its weight the worst this can do is turn it into a solid sphere and cost it a third of its speed. A bubble migrating in a temperature gradient has no such floor. Its own surface is the engine, and a cap removes the engine as well as raising the drag. A cap over the cold hemisphere leaves a rising bubble three-quarters of its speed and a migrating one a fifth; a cap of 120° leaves the migrating bubble four per cent. The surfactant it takes is set by the tension difference that drives the migration, and that is tiny.

viscous · Mobile interface

Named alongside it

The objects these essays reach for when they reach for this one.

Boundary conditionBubbleDrag coefficientHadamard rybczynskiMarangoniModel limitSingularityStokes flowCreeping flowDissipationDragDrop

All concepts