Concept

Kinetic theory — where it appears

The description of a gas as molecules flying freely between collisions, through the distribution of their velocities at each point. Viscosity, conduction and slip all follow from it, and it still holds where the continuum equations fail, at free paths comparable with the flow's size.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

How wrong the ordinary answer already is. The error in a no-slip continuum calculation of the flow through a channel, against the Knudsen number, both logarithmic. The rule at Kn = 1 is where a molecule crosses the whole channel between collisions — the value the number is named for. The error is one per cent at Kn = 1/594, five per cent at 1/114 and ten at 1/54, so the continuum regime of the usual classification, which runs to Kn = 0.01, is a region in which the continuum answer is already six per cent out at its far end.

Where a fluid stops being one

The Knudsen number is the mean free path over the size of the thing, and at one a molecule crosses the whole channel between collisions. The continuum equations with a no-slip wall are already one per cent wrong at one part in five hundred and ninety-four, which is a factor nothing about the definition would suggest.

regimes · Knudsen
Sheared between plates, a gas transmits its full viscous stress down to a few free paths across, and then a share proportional to its pressure. The shear stress a gas transmits between two plates, over Navier–Stokes's μU/H, against the rarefaction δ = √π/(2Kn), from the linearised kinetic equation; with Navier–Stokes and first-order slip, 1/(1 + 2·1.016/δ), and the free-molecular δ/√π. The kinetic stress is 0.908 of μU/H at δ = 20, 0.501 at 2, 0.0979 at 0.2; the slip formula is within 2.7 per cent at δ = 1.

A gas's viscosity ignores its pressure until the free path reaches the walls

Maxwell predicted in 1860 that a gas's viscosity does not depend on its density — halve the pressure and half as many molecules carry momentum across the flow, each twice as far — and measured it with swinging discs in 1866: unchanged from an atmosphere to a sixtieth of one. Solved across every pressure with the kinetic equation, the shear a gas transmits between two plates obeys him over five decades and then, once the free path reaches the gap, falls in proportion to the pressure. A millimetre gap reads half the true viscosity at fifteen pascals, and a vacuum gauge reads pressure from exactly that fall.

kinematics · Continuum
Between plates the flow rate falls with rarefaction to a minimum near one free path across, then climbs without limit. The reduced flow rate G of a gas driven by a pressure gradient between two plates, against the rarefaction parameter δ = √π/(2Kn), from the linearised BGK equation; beside it Navier–Stokes with no slip (δ/6), with Maxwell's slip (δ/6 + 1.016) and the uncollided flux of molecules straight from a wall. The least flow rate is 1.538 at δ = 1.07, Kn = 0.827; at δ = 0.01 the solve gives 3.049, at δ = 0.001 4.449 and at δ = 10 2.769.

A thinning gas flows least at one free path across, and then more without end

Pump the gas out of a narrow channel and, for the same pressure gradient, less of it flows — until the channel is about one mean free path high. Thinner than that, more flows, and between infinite plates the flow rate climbs without limit, because the molecules carrying it are the ones skimming along the walls, whose flights only collisions with other molecules can end. Knudsen measured the minimum in 1909. The linearised kinetic equation puts it at a reduced flow rate of 1.538, at a Knudsen number of 0.83, and shows it is not a dip below the two closed forms but a place far above both.

regimes · Knudsen

Named alongside it

The objects these essays reach for when they reach for this one.

ContinuumKnudsen numberMean free pathSlipBoundary conditionModel validityViscosityAsymptoticsDimensionlessMeasurementPoiseuille flowShear stress

All concepts